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Merck
CN

375934

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide

≥95%, with 1% tert-Butyldimethylchlorosilane

别名:

MTBSTFA+TBDMSCl, 99:1, N-甲基-N-叔丁基二甲基甲硅烷基三氟乙酰胺, MTBSTFA + 1% TBDMSCl, 甲硅烷基化混合物VI

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关于此项目

经验公式(希尔记法):
C9H18F3NOSi
化学文摘社编号:
分子量:
241.33
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22
Beilstein/REAXYS Number:
3606546
MDL number:
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产品名称

N-叔丁基二甲基甲硅烷基-N-甲基三氟乙酰胺,含 1% 叔丁基二甲基氯硅烷, ≥95%

SMILES string

CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C

InChI

1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3

InChI key

QRKUHYFDBWGLHJ-UHFFFAOYSA-N

assay

≥95%

form

liquid

contains

1% TBDMSCl

functional group

amine
fluoro

storage temp.

−20°C

Quality Level

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Application

N--丁基二甲基甲硅烷基-N-甲基三氟乙酰胺与1%的 -丁基二甲基氯硅烷通常用于制备N--丁基二甲基甲硅烷基乙醇胺,其是氮芥类物质水解生成的产物。。它还可用于N,O-二酰基羟胺的选择性 O-甲硅烷基化。

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Organometallics, 23, 2157-2161 (2004)
Tsubasa Nakajima et al.
Plant & cell physiology, 55(9), 1605-1612 (2014-06-28)
Cyanobacteria have flexible metabolic capability that enables them to adapt to various environments. To investigate their underlying metabolic regulation mechanisms, we performed an integrated analysis of metabolic flux using transcriptomic and metabolomic data of a cyanobacterium Synechocystis sp. PCC 6803
A Royer et al.
Journal of chromatography. A, 1108(1), 129-135 (2006-01-31)
An analytical method has been developed for the determination of residues of ethephon (2-chloroethyl phosphonic acid) in drinking and surface water. The procedure is based on de-ionisation with an anion/cation-exchange resin, solid phase extraction by means of anion-exchange polystyrene-divinylbenzene extraction
Xiaowei Wang et al.
Analytica chimica acta, 753, 57-63 (2012-10-31)
A sample preparation method for the determination of hydroxylated polycyclic aromatic hydrocarbons (OH-PAHs) in sediment samples was developed using gas chromatography-mass spectrometry (GC-MS). Dispersive liquid-liquid microextraction (DLLME) with derivatization was performed following the subcritical water extraction (SWE) that provided which
Xiaodong Huang et al.
Analytical chemistry, 80(1), 107-114 (2007-12-07)
This work describes an approach to differential metabolomics that involves stable isotope labeling for relative quantification as part of sample analysis by two-dimensional gas chromatography/mass spectrometry (GCxGC/MS). The polar metabolome in control and experimental samples was extracted and differentially derivatized

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Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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