跳转至内容
Merck
CN

T511609

Sigma-Aldrich

(S)-TCYP

AldrichCPR

登录查看公司和协议定价

经验公式(希尔记法):
C68H81O4P
分子量:
993.34
UNSPSC代码:
12352200

质量水平

反应适用性

reagent type: ligand

折射率

n/D

官能团

phosphine

SMILES字符串

OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)C6CCCCC6)C7CCCCC7

一般描述

(S)-TCYP is a chiral phosphoric acid catalyst that is commonly used in chemical synthesis. It has been found to be particularly effective in promoting enantioselective reactions. The sterically demanding triscyclohexylbenzene at the 3 and 3′ positions of (S)-TCYP contribute significant steric influence and ressult in its to its high levels of enantioselectivity.

应用

(S)-TCYP has been used in asymmetric aza-ene-type reactions, catalyzing the formation of C-C bonds with high levels of diastereoselectivity

其他说明

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ (Lot或Batch)字后找到。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Understanding the Mechanism of the Asymmetric Propargylation of Aldehydes Promoted by 1,1?-Bi-2-Naphthol-Derived Catalysts
Grayson, M. N.; Goodman, J. M.
Journal of the American Chemical Society, 135, 6142-6148 (2013)
Mechanistic Insights into the BINOL-Derived Phosphoric Acid-Catalyzed Asymmetric Allylboration of Aldehydes
Grayson, M. N.; Pellegrinet, S. C.; Goodman, J. M.
Journal of the American Chemical Society, 134, 2716?2722- 2716?2722 (2012)

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门