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Merck
CN

L511692

Sigma-Aldrich

2:1 2,2′-联吡啶:六氟磷酸环戊二烯基(n6-萘)钌(II)

AldrichCPR

别名:

Herzon Hydration Catalyst

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About This Item

经验公式(希尔记法):
C25H21N2Ru · PF6
分子量:
595.48
UNSPSC代码:
12352200
PubChem化学物质编号:

质量水平

SMILES字符串

F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=CC=CC=N1.C3(C4=NC=CC=C4)=CC=CC=N3.[C]56[C][C][C][C][C]5C=CC=C6.[Ru+].[C]7[C][C][C][C]7

InChI

1S/2C10H8N2.C10H8.C5H5.F6P.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2-6-10-8-4-3-7-9(10)5-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-8H;1-8H;1-5H;;/q;;;;-1;+1

InChI key

YFGQTOCRCOVSBH-UHFFFAOYSA-N

应用

Ready mixed, single catalyst system developed by the Herzon Group for terminal alkyne functionalization. Used recently by that group to affect the anti-Markovnikov reductive hydration alkynes.

Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes

其他说明

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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相关内容

The Herzon group has developed highly active catalysts for the anti-Markovnikov hydration and reductive hydration of terminal alkynes to form aldehydes and linear alcohols, respectively.

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