H54409
反式 -4-羟基- L -脯氨酸
≥99%, for peptide synthesis
别名:
(2S,4R)-4-羟基吡咯烷-2-羧酸, Hyp
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经验公式（希尔记法）:
C5H9NO3
化学文摘社编号:
分子量:
131.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
EC Number:
200-091-9
MDL number:
Beilstein/REAXYS Number:
81441
产品名称
反式 -4-羟基- L -脯氨酸, ≥99%
InChI key
PMMYEEVYMWASQN-DMTCNVIQSA-N
InChI
1S/C5H9NO3/c7-3-1-4(5(8)9)6-2-3/h3-4,6-7H,1-2H2,(H,8,9)/t3-,4+/m1/s1
SMILES string
O[C@H]1CN[C@@H](C1)C(O)=O
assay
≥99%
form
crystalline powder
optical activity
[α]25/D −75.6°, c = 1 in H2O
reaction suitability
reaction type: solution phase peptide synthesis
color
white to off-white
mp
273 °C (dec.) (lit.)
application(s)
peptide synthesis
Quality Level
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Application
合成神经兴奋 kainoid 和抗真菌棘白菌素的多功能试剂。也可用于合成手性配体，该配体可用于醛的不对称乙基化。
General description
反式-4-羟基-L-脯氨酸是羟基脯氨酸的异构体，可用作许多药物（如神经兴奋性kainoid）生产的手性合成砌块。
Other Notes
动物结构蛋白（如胶原和弹性蛋白）的天然成分。
存储类别
11 - Combustible Solids
wgk
WGK 1
ppe
Eyeshields, Gloves, type N95 (US)
Tetrahedron, 49, 6195-6195 (1993)
Synthetic Communications, 23, 2691-2691 (1993)
Biosynthesis of trans-4-hydroxyproline by recombinant strains of Corynebacterium glutamicum and Escherichia coli
Yi Y, et al.
BMC biotechnology, 14, 1-8 (2014)
Tetrahedron Letters, 35, 6163-6163 (1994)
Stefan de Vries et al.
Tissue engineering. Part A, 25(11-12), 830-841 (2018-05-10)
Notochordal cells (NCs) reside in the core of the healthy disc and produce soluble factors that can stimulate nucleus pulposus cells (NPCs). These NC-derived factors may be applied in intervertebral disc regeneration for treatment of low-back pain. However, identification of
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