G6600
甘氨酸甲酯 盐酸盐
99%, for peptide synthesis
别名:
Glycine methyl ester·HCl, Methyl glycinate hydrochloride
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关于此项目
线性分子式:
NH2CH2COOCH3 · HCl
化学文摘社编号:
分子量:
125.55
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352209
EC Number:
227-139-1
MDL number:
Beilstein/REAXYS Number:
3593644
产品名称
甘氨酸甲酯 盐酸盐, 99%
InChI key
COQRGFWWJBEXRC-UHFFFAOYSA-N
InChI
1S/C3H7NO2.ClH/c1-6-3(5)2-4;/h2,4H2,1H3;1H
SMILES string
Cl.COC(=O)CN
assay
99%
form
powder, crystals or chunks
reaction suitability
reaction type: solution phase peptide synthesis
color
white
mp
175 °C (dec.) (lit.)
application(s)
peptide synthesis
Quality Level
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Application
甘氨酸甲酯盐酸盐可用于合成以氨基酸酯为侧链的环磷腈类物质。还可在水相中合成多肽，是一种绿色的制肽法。
General description
甘氨酸甲酯盐酸盐又名甲基甘氨酸酯盐酸盐，是一种甘氨酸衍生物，用于制备氨基酸和有机化合物。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
A green protocol for peptide bond formation in WEB
M Konwar
Tetrahedron Letters, 57, 2283-2285 (2016)
The investigation of thermosensitive properties of phosphazene derivatives bearing amino acid ester groups
A Uslu
Journal of Molecular Structure, 1136, 90-99 (2017)
J M Delfino et al.
International journal of peptide and protein research, 21(4), 440-450 (1983-04-01)
The reactivity of the carboxyl groups in bovine growth hormone was studied by reaction with 1-ethyl-3(3-dimethylaminopropyl) carbodiimide in the presence of an excess of glycinemethylester. Localization in the molecule of the various kinetically distinguishable carboxyl groups was achieved. Highest reactivity
Vincenzo Santagada et al.
Journal of combinatorial chemistry, 7(4), 618-621 (2005-07-12)
An easy and convenient microwave-assisted synthesis of N-alkylated glycine methyl esters is described. Parallel and nonparallel combinatorial methods are described and compared. The described reactions are reductive alkylations of several aldehydes and glycine methyl ester in the presence of NaBH3CN.
Glycine enolates: the large effect of iminium ion formation on alpha-amino carbon acidity.
A Rios et al.
Journal of the American Chemical Society, 123(32), 7949-7950 (2001-08-09)
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