product name
甘氨酸甲酯 盐酸盐, 99%
质量水平
检测方案
99%
形式
powder, crystals or chunks
反应适用性
reaction type: solution phase peptide synthesis
颜色
white
mp
175 °C (dec.) (lit.)
应用
peptide synthesis
SMILES字符串
Cl.COC(=O)CN
InChI
1S/C3H7NO2.ClH/c1-6-3(5)2-4;/h2,4H2,1H3;1H
InChI key
COQRGFWWJBEXRC-UHFFFAOYSA-N
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一般描述
甘氨酸甲酯盐酸盐又名甲基甘氨酸酯盐酸盐，是一种甘氨酸衍生物，用于制备氨基酸和有机化合物。
应用
甘氨酸甲酯盐酸盐可用于合成以氨基酸酯为侧链的环磷腈类物质。还可在水相中合成多肽，是一种绿色的制肽法。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
A green protocol for peptide bond formation in WEB
M Konwar
Tetrahedron Letters, 57, 2283-2285 (2016)
The investigation of thermosensitive properties of phosphazene derivatives bearing amino acid ester groups
A Uslu
Journal of Molecular Structure, 1136, 90-99 (2017)
J M Delfino et al.
International journal of peptide and protein research, 21(4), 440-450 (1983-04-01)
The reactivity of the carboxyl groups in bovine growth hormone was studied by reaction with 1-ethyl-3(3-dimethylaminopropyl) carbodiimide in the presence of an excess of glycinemethylester. Localization in the molecule of the various kinetically distinguishable carboxyl groups was achieved. Highest reactivity
Vincenzo Santagada et al.
Journal of combinatorial chemistry, 7(4), 618-621 (2005-07-12)
An easy and convenient microwave-assisted synthesis of N-alkylated glycine methyl esters is described. Parallel and nonparallel combinatorial methods are described and compared. The described reactions are reductive alkylations of several aldehydes and glycine methyl ester in the presence of NaBH3CN.
L K Frankel et al.
Biochemistry, 38(43), 14271-14278 (1999-11-26)
The effects of the modification of carboxylate groups on the manganese-stabilizing protein of photosystem II were investigated. Carboxylate groups (including possibly the C-terminus) on the manganese-stabilizing protein were modified with glycine methyl ester in a reaction facilitated by 1-ethyl-3-[3-(dimethylamino)propyl]carbodiimide. The
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