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Merck
CN

E14403

Sigma-Aldrich

2-溴-2-甲基丙酸乙酯

98%

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别名:
α-溴异丁酸乙酯
线性分子式:
(CH3)2CBrCOOC2H5
CAS号:
分子量:
195.05
Beilstein:
1098947
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

liquid

折射率

n20/D 1.444 (lit.)

bp

65-67 °C/11 mmHg (lit.)

密度

1.329 g/mL at 25 °C (lit.)

SMILES字符串

CCOC(=O)C(C)(C)Br

InChI

1S/C6H11BrO2/c1-4-9-5(8)6(2,3)7/h4H2,1-3H3

InChI key

IOLQWGVDEFWYNP-UHFFFAOYSA-N

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一般描述

α-溴异丁酸乙酯是一种有机溴酯,可用作受控自由基聚合反应中的抑制剂。

应用

原子转移自由基聚合(ATRP)引发剂,其将产生具有乙基端基的聚合物。

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3

WGK

WGK 3

闪点(°F)

140.0 °F

闪点(°C)

60 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Na Wang et al.
Analytical methods : advancing methods and applications, 12(36), 4438-4446 (2020-08-29)
As robust functional polymers, polymer brush-based hybrid nanomaterials have potential application in the highly sensitive determination of tumor markers (TMs). Currently, there are plentiful reports on the polymerization methods of functional polymer brushes. Low ppm ATRP (activators (re)generated by electron
Katarzyna Niesyto et al.
International journal of molecular sciences, 22(1) (2021-01-06)
In this study, drug nanocarriers were designed using linear copolymers with different contents of cholinium-based ionic liquid units, i.e., [2-(methacryloyloxy)ethyl]trimethylammonium chloride (TMAMA/Cl: 25, 50, and 75 mol%). The amphiphilicity of the copolymers was evaluated on the basis of their critical
Dongpo Xu et al.
Analytical and bioanalytical chemistry, 412(30), 8371-8378 (2020-10-04)
In this study, a simple and efficient strategy for the construction of hydrangea-like mesoporous WO3 nanoflowers templated using diblock copolymer PS119-PtBA129 was developed. The nanoflower shows good gas sensing properties, especially for 3-hydroxy-2-butanone (3H-2B), which is the signature metabolite of
Hailing He et al.
Materials (Basel, Switzerland), 12(16) (2019-08-10)
The balance of strengthening and toughening of poly (lactic acid) (PLA) has been an intractable challenge of PLA nanocomposite development for many years. In this paper, core-shell nanoparticles consisting of a silica rigid core and poly (butyl acrylate) (PBA) flexible
Wojciech Raj et al.
Nanomaterials (Basel, Switzerland), 10(3) (2020-03-21)
A totally new approach in the synthesis of mixed polymer brushes tethered on polyamide (PA) surfaces is presented herein. As a proof of concept, two types of homopolymers were synthesized in sequential surface-initiated atom transfer radical polymerization (SI-ATRP) reactions: poly(methyl

商品

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

实验方案

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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