E14403
2-溴-2-甲基丙酸乙酯
98%
别名:
α-溴异丁酸乙酯
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关于此项目
线性分子式:
(CH3)2CBrCOOC2H5
化学文摘社编号:
分子量:
195.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-980-6
Beilstein/REAXYS Number:
1098947
MDL number:
产品名称
2-溴-2-甲基丙酸乙酯, 98%
InChI key
IOLQWGVDEFWYNP-UHFFFAOYSA-N
InChI
1S/C6H11BrO2/c1-4-9-5(8)6(2,3)7/h4H2,1-3H3
SMILES string
CCOC(=O)C(C)(C)Br
assay
98%
form
liquid
refractive index
n20/D 1.444 (lit.)
bp
65-67 °C/11 mmHg (lit.)
density
1.329 g/mL at 25 °C (lit.)
Quality Level
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Application
原子转移自由基聚合（ATRP）引发剂，其将产生具有乙基端基的聚合物。
General description
α-溴异丁酸乙酯是一种有机溴酯，可用作受控自由基聚合反应中的抑制剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
140.0 °F - closed cup
flash_point_c
60 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Dongpo Xu et al.
Analytical and bioanalytical chemistry, 412(30), 8371-8378 (2020-10-04)
In this study, a simple and efficient strategy for the construction of hydrangea-like mesoporous WO3 nanoflowers templated using diblock copolymer PS119-PtBA129 was developed. The nanoflower shows good gas sensing properties, especially for 3-hydroxy-2-butanone (3H-2B), which is the signature metabolite of
Na Wang et al.
Analytical methods : advancing methods and applications, 12(36), 4438-4446 (2020-08-29)
As robust functional polymers, polymer brush-based hybrid nanomaterials have potential application in the highly sensitive determination of tumor markers (TMs). Currently, there are plentiful reports on the polymerization methods of functional polymer brushes. Low ppm ATRP (activators (re)generated by electron
Katarzyna Niesyto et al.
International journal of molecular sciences, 22(1) (2021-01-06)
In this study, drug nanocarriers were designed using linear copolymers with different contents of cholinium-based ionic liquid units, i.e., [2-(methacryloyloxy)ethyl]trimethylammonium chloride (TMAMA/Cl: 25, 50, and 75 mol%). The amphiphilicity of the copolymers was evaluated on the basis of their critical
Hailing He et al.
Materials (Basel, Switzerland), 12(16) (2019-08-10)
The balance of strengthening and toughening of poly (lactic acid) (PLA) has been an intractable challenge of PLA nanocomposite development for many years. In this paper, core-shell nanoparticles consisting of a silica rigid core and poly (butyl acrylate) (PBA) flexible
Wojciech Raj et al.
Nanomaterials (Basel, Switzerland), 10(3) (2020-03-21)
A totally new approach in the synthesis of mixed polymer brushes tethered on polyamide (PA) surfaces is presented herein. As a proof of concept, two types of homopolymers were synthesized in sequential surface-initiated atom transfer radical polymerization (SI-ATRP) reactions: poly(methyl
商品
ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.
实验方案
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
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