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受控自由基聚合
可控自由基聚合（CRP）技术能够更精确地调控聚合物分子量、分子量分布、官能度及组成。该技术适用于开发具有特定性能的精确定义聚合物。通过采用多种乙烯基单体，CRP可构建适用于不同应用场景的多元性能聚合物。
CRP技术包含三种基础方法：
- 原子转移自由基聚合（ATRP）
- 可逆加成/断裂链转移（RAFT）聚合
- 过氧亚硝酸酯介导聚合（NMP）
我们提供全面的乙烯基单体、降冰片烯单体、RAFT引发剂、ATRP引发剂及NMP引发剂产品组合，满足各类受控自由基聚合需求。各方法的技术综述与支持信息详见《受控自由基聚合指南》。
相关资源
- Brochure: Controlled Radical Polymerization Guide
This guide provides a fundamental review of ATRP, RAFT, and NMP techniques, as well as corresponding procedures and product information to utilize these techniques.
- Applications: Free Radical Initiators
A photoinitiator is a compound especially added to a formulation to convert absorbed light energy, UV or visible light, into chemical energy in the form of initiating species, viz., free radicals or cations.
- Article: RAFT Agents for Making Well-Defined Functionalized Polymers
Low-cost, high-purity RAFT Agents are vital for industrial RAFT polymerization. We supply effective agents for this technology.
- Article: RAFT- Choosing the Right Agent to Achieve Controlled Polymerization
查找可逆加成-断裂链转移(RAFT)工艺、RAFT剂和应用分类。
- Article: Universal (Switchable) RAFT Agents for Well-Defined Block Copolymers
Universal (Switchable) RAFT agents allow for the polymerization of both less activated and more activated monomers and are ideal for the synthesis of well-defined block copolymers.
- Article: Block Copolymer Synthesis Using a Nitroxide-mediated Radical
Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator
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