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质量水平
检测方案
97%
形式
liquid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.597 (lit.)
bp
222 °C/759 mmHg (lit.)
mp
−51 °C (lit.)
密度
1.319 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
ClP(Cl)c1ccccc1
InChI
1S/C6H5Cl2P/c7-9(8)6-4-2-1-3-5-6/h1-5H
InChI key
IMDXZWRLUZPMDH-UHFFFAOYSA-N
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一般描述
P,P-苯基二氯化膦(DCPP)是有机合成的重要试剂。广泛用于制备阻燃剂、尼龙稳定剂、增塑剂和有机磷化合物。可在无水氯化铝催化剂的存在下，由三氯化磷和苯经由Friedel-Craft反应制备而成。
应用
P,P-苯基二氯化膦可作为反应剂合成外消旋[1]二茂铁环蕃化合物（顺反异构体混合物）。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Insight into the Thermal Ring-Opening Polymerization of Phospha [1] ferrocenophanes
Khozeimeh S, et al.
Chemistry?A European Journal , 22(47), 16838-16849 (2016)
Preparation of dichlorophenylphosphine via Friedel--Crafts reaction in ionic liquids
Wang ZW,et al.
Green Chemistry, 5(6), 737-739 (2003)
Jan Hynek et al.
Organic & biomolecular chemistry, 16(39), 7274-7281 (2018-09-28)
The development of effective photosensitizers is particularly attractive for photodynamic therapy of cancer. Three novel porphyrin photosensitizers functionalized with phosphinic groups were synthesized and their physicochemical, photophysical, and photobiological properties were collected. Phosphinic acid groups (R1R2POOH) attached to the porphyrin
Paul A Gray et al.
Dalton transactions (Cambridge, England : 2003), 45(5), 2124-2129 (2015-10-23)
A series of 2-phosphino-1,3-diphosphonium trifluoromethanesulfonate salts has been prepared and comprehensively characterized. The compounds represent rare examples of salts containing triphosphorus dications and establish important structural and spectroscopic parameters and trends for catenated phosphorus chains.
G Bas de Jong et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(68), 15944-15952 (2020-07-01)
In this paper, we highlight the synthesis of a variety of primary phosphine-boranes (RPH2 ⋅BH3 ) from the corresponding dichlorophosphines, simply by using Li[BH4 ] as reductant and provider of the BH3 protecting group. The method offers facile access not
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