C87851
乙酰丙酮酸铜
97%
别名:
2,4-戊二酮 铜(II) 衍生物, 2,4-戊二酮铜(II), Cu(acac)2, 乙酰丙酮铜
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关于此项目
线性分子式:
Cu(C5H7O2)2
化学文摘社编号:
分子量:
261.76
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
236-477-9
Beilstein/REAXYS Number:
4157957
MDL number:
InChI key
QYJPSWYYEKYVEJ-FDGPNNRMSA-L
InChI
1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
SMILES string
CC(=O)\C=C(\C)O[Cu]O\C(C)=C/C(C)=O
assay
97%
form
powder
reaction suitability
core: copper, reagent type: catalyst
mp
284-288 °C (dec.) (lit.)
Quality Level
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General description
乙酰丙酮酸铜(Cu(acac)2)是一种有机金属化合物，特有较低的热分解温度286 °C，适合作为前体合成铜和氧化铜纳米颗粒。它可用于电子、陶瓷和催化领域。
Application
- 作为奖励缺陷调节剂的右美沙芬：研究探讨了在MDMA治疗的动物中右美沙芬在调节与5-羟色胺转运体可用性相关的奖励缺陷中的作用，表明其在神经精神药理学和成瘾研究中的潜在应用（Chiu et al., 2024）。
- 靶向GABA谷氨酸神经传递的药物疗法：该综述讨论了右美沙芬在靶向GABA谷氨酸神经传递治疗难治性抑郁症的药物疗法中的用途，强调了其作为NMDA受体拮抗剂和sigma-1受体激动剂的作用（Vecera et al., 2023）。
- 经验依赖性心理效应：一项双盲研究比较了右美沙芬和裸盖菇素对健康志愿者的心理效应，考察了它们经验依赖性和持久性影响，该研究与临床心理学和迷幻药研究相关（Mathai et al., 2023）。
乙酰丙酮酸铜可用于：
- 作为前体合成铜基硫系化合物Cu2NiSnS4 CNTS纳米晶体，结合金纳米颗粒(Au NPs)后可形成核壳型结构。得到的Au/CNTS纳米晶体可作为光活性材料制作混合光电探测器件，呈现优越的光电性能，例如可见光谱中的高响应性和比探测率。
- 作为前体通过高温注射法合成Cu-Ga-Zn-S纳米棒，用于高效的光催化水分解。
- 作为铜前体通过一锅合成核/壳PtCu纳米颗粒。这种双金属PtCu纳米颗粒催化氧还原反应的活性更高。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Zhan'ao Tan et al.
Physical chemistry chemical physics : PCCP, 14(42), 14589-14595 (2012-09-28)
A solution-processed vanadium oxide (s-VO(x)) anode buffer layer on an indium-tin-oxide (ITO) electrode was used instead of PEDOT:PSS for improving the stability and photovoltaic performance of the polymer solar cells (PSCs). The s-VO(x) layer was prepared by spin-coating a vanadyl
Nan Tian et al.
Dalton transactions (Cambridge, England : 2003), 39(37), 8613-8615 (2010-08-19)
The design, synthesis, photophysical and significantly improved electrooptical properties of a series of red emitting cyclometalated iridium(iii) complexes containing carbazolyl-acetylacetonate ligands are described.
Gong-Jun Chen et al.
Dalton transactions (Cambridge, England : 2003), 39(44), 10637-10643 (2010-10-06)
Two Eu(III) complexes, [Eu(acac)(3)(dpq)] (1) and [Eu(acac)(3)(dppz)] CH(3)OH (2) {viz. acetylacetonate (acac), dipyrido[3,2-d:20,30-f]quinoxaline (dpq), dipyrido[3,2-a:20,30-c] phenazine (dppz)}, have been synthesized and their DNA binding, photo-induced DNA cleavage activity and cell cytotoxicity are studied. The complexes display significant binding propensity to
Gui-Ge Hou et al.
Chemical communications (Cambridge, England), 47(38), 10731-10733 (2011-08-27)
Two NbO-type MOFs based on ditopic pyridyl substituted diketonate ligands were reported. One exhibits a reversible SC-SC water encapsulation, while the other shows an interesting guest-driven luminescent property based on M(III) acetylacetonate (M = Eu and Fe) guest species.
Chih-Chia Huang et al.
Chemical communications (Cambridge, England), (23)(23), 3360-3362 (2009-06-09)
A general approach involving a solvothermal method was developed to synthesize a series of silicate nanoshells (<100 nm) where both Gd silicate and Gd silicate:Eu nanoshells were further demonstrated to exhibit dual-modality MRI and optical imaging functions.
商品
Copper metal deposition processes are an essential tool for depositing interconnects used in microelectronic applications, giving group 11 (coinage metals: Copper, Silver, and Gold) an important place in atomic layer deposition (ALD) process development.
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