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Merck
CN

C71203

Sigma-Aldrich

4-氯苯乙烯

97%, contains 500 ppm 4-tert-butylcatechol as inhibitor

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About This Item

线性分子式:
H2C=CHC6H4Cl
CAS号:
分子量:
138.59
Beilstein:
1098859
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

蒸汽压

0.68 mmHg ( 20 °C)

质量水平

方案

97%

表单

liquid

包含

500 ppm 4-tert-butylcatechol as inhibitor

折射率

n20/D 1.565 (lit.)

沸点

192 °C (lit.)

密度

1.155 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

Clc1ccc(C=C)cc1

InChI

1S/C8H7Cl/c1-2-7-3-5-8(9)6-4-7/h2-6H,1H2

InChI key

KTZVZZJJVJQZHV-UHFFFAOYSA-N

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一般描述

4-氯苯乙烯是一种对位卤代苯乙烯衍生物。在过氧化苯甲酰(引发剂)存在下,它与丙烯腈(AN)接枝共聚到乙烯-丙烯-二烯三元共聚物(EPDM)上。

应用

4-氯芘被用于以下研究:
  • 通过结构活性关系(SAR)的发展研究苯乙烯乙烯基的化学和生化特性。
  • 新型铜(I)双(吡唑基)硼原子的烯烃配合物的制备。
  • 研究4-取代苯乙烯的阳离子Heck反应中的区域选择性。

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Aquatic Chronic 2 - Skin Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

154.4 °F - closed cup

闪点(°C)

68 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Guido Pampaloni et al.
Dalton transactions (Cambridge, England : 2003), (29)(29), 3576-3583 (2006-07-21)
New bis(pyrazolyl)borato olefin complexes of copper(I) of general formula Cu[BH2(3,5-(CF3)2Pz)2](olefin) have been prepared (olefins: coe = cyclooctene, van = 4-vinylanisole, clsty = 4-chlorostyrene, tevs = triethylvinylsilane, fn = fumaronitrile). The structures of Cu[BH2(3,5-(CF3)2Pz)2](L), L = coe, van, tevs, fn, have
Reactivity and regioselectivity in the Heck reaction: Hammett study of 4-substituted styrenes.
Fristrup P, et al.
Organometallics, 23(26), 6160-6165 (2004)
Synthesis and properties of acrylonitrile-EPDM-4-chlorostyrene graft copolymer.
Park D-J, et al.
Journal of Applied Polymer Science, 44(4), 727-735 (1992)
Wei Chen et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 29(2), 152-153 (2011-05-31)
To establish a rapid gas chromatographic method for determination of o-chlorostyrene in the air of workplace. The air samples were collected by syringes, injected directly to the GC system, and then separated by a FFAP capillary column (30 m ×
Jou-Ku Chung et al.
Toxicology letters, 210(3), 353-359 (2012-03-01)
Styrene is one of the most important industrial intermediates consumed in the world and is mainly used as a monomer for reinforced plastics and rubber. Styrene has been found to be hepatotoxic and pneumotoxic in humans and experimental animals. The

商品

Heck反应是烯烃与芳基或乙烯基卤化物(或三氟甲磺酸酯)之间的钯催化交叉偶联反应,用于生成取代的烯烃。

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