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Merck
CN

C71203

Sigma-Aldrich

4-氯苯乙烯

97%, contains 500 ppm 4-tert-butylcatechol as inhibitor

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About This Item

线性分子式:
H2C=CHC6H4Cl
CAS号:
分子量:
138.59
Beilstein:
1098859
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

蒸汽压

0.68 mmHg ( 20 °C)

质量水平

方案

97%

表单

liquid

包含

500 ppm 4-tert-butylcatechol as inhibitor

折射率

n20/D 1.565 (lit.)

沸点

192 °C (lit.)

密度

1.155 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

Clc1ccc(C=C)cc1

InChI

1S/C8H7Cl/c1-2-7-3-5-8(9)6-4-7/h2-6H,1H2

InChI key

KTZVZZJJVJQZHV-UHFFFAOYSA-N

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一般描述

4-氯苯乙烯是一种对位卤代苯乙烯衍生物。在过氧化苯甲酰(引发剂)存在下,它与丙烯腈(AN)接枝共聚到乙烯-丙烯-二烯三元共聚物(EPDM)上。

应用

4-氯芘被用于以下研究:
  • 通过结构活性关系(SAR)的发展研究苯乙烯乙烯基的化学和生化特性。
  • 新型铜(I)双(吡唑基)硼原子的烯烃配合物的制备。
  • 研究4-取代苯乙烯的阳离子Heck反应中的区域选择性。

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Aquatic Chronic 2 - Skin Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

154.4 °F - closed cup

闪点(°C)

68 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Wei Chen et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 29(2), 152-153 (2011-05-31)
To establish a rapid gas chromatographic method for determination of o-chlorostyrene in the air of workplace. The air samples were collected by syringes, injected directly to the GC system, and then separated by a FFAP capillary column (30 m ×
Reactivity and regioselectivity in the Heck reaction: Hammett study of 4-substituted styrenes.
Fristrup P, et al.
Organometallics, 23(26), 6160-6165 (2004)
Synthesis and properties of acrylonitrile-EPDM-4-chlorostyrene graft copolymer.
Park D-J, et al.
Journal of Applied Polymer Science, 44(4), 727-735 (1992)
Guido Pampaloni et al.
Dalton transactions (Cambridge, England : 2003), (29)(29), 3576-3583 (2006-07-21)
New bis(pyrazolyl)borato olefin complexes of copper(I) of general formula Cu[BH2(3,5-(CF3)2Pz)2](olefin) have been prepared (olefins: coe = cyclooctene, van = 4-vinylanisole, clsty = 4-chlorostyrene, tevs = triethylvinylsilane, fn = fumaronitrile). The structures of Cu[BH2(3,5-(CF3)2Pz)2](L), L = coe, van, tevs, fn, have
Małgorzata Bołt et al.
Materials (Basel, Switzerland), 13(18) (2020-09-12)
Bifunctional silsesquioxanes create an attractive group of compounds with a wide range of potential applications, and recently they have gained much interest. They are known to be obtained mainly via hydrosilylation, but we disclose novel synthetic protocols based on different

商品

Heck反应是烯烃与芳基或乙烯基卤化物(或三氟甲磺酸酯)之间的钯催化交叉偶联反应,用于生成取代的烯烃。

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