C71203
4-氯苯乙烯
97%, contains 500 ppm 4-tert-butylcatechol as inhibitor
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线性分子式:
H2C=CHC6H4Cl
化学文摘社编号:
分子量:
138.59
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
214-028-8
Beilstein/REAXYS Number:
1098859
MDL number:
InChI key
KTZVZZJJVJQZHV-UHFFFAOYSA-N
InChI
1S/C8H7Cl/c1-2-7-3-5-8(9)6-4-7/h2-6H,1H2
SMILES string
Clc1ccc(C=C)cc1
vapor pressure
0.68 mmHg ( 20 °C)
assay
97%
form
liquid
contains
500 ppm 4-tert-butylcatechol as inhibitor
Quality Level
bp
192 °C (lit.)
density
1.155 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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General description
4-氯苯乙烯是一种对位卤代苯乙烯衍生物。在过氧化苯甲酰（引发剂）存在下，它与丙烯腈（AN）接枝共聚到乙烯-丙烯-二烯三元共聚物（EPDM）上。
Application
4-氯芘被用于以下研究：
- 通过结构活性关系（SAR）的发展研究苯乙烯乙烯基的化学和生化特性。
- 新型铜（I）双（吡唑基）硼原子的烯烃配合物的制备。
- 研究4-取代苯乙烯的阳离子Heck反应中的区域选择性。
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
154.4 °F - closed cup
flash_point_c
68 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Wei Chen et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 29(2), 152-153 (2011-05-31)
To establish a rapid gas chromatographic method for determination of o-chlorostyrene in the air of workplace. The air samples were collected by syringes, injected directly to the GC system, and then separated by a FFAP capillary column (30 m ×
Guido Pampaloni et al.
Dalton transactions (Cambridge, England : 2003), (29)(29), 3576-3583 (2006-07-21)
New bis(pyrazolyl)borato olefin complexes of copper(I) of general formula Cu[BH2(3,5-(CF3)2Pz)2](olefin) have been prepared (olefins: coe = cyclooctene, van = 4-vinylanisole, clsty = 4-chlorostyrene, tevs = triethylvinylsilane, fn = fumaronitrile). The structures of Cu[BH2(3,5-(CF3)2Pz)2](L), L = coe, van, tevs, fn, have
Synthesis and properties of acrylonitrile-EPDM-4-chlorostyrene graft copolymer.
Park D-J, et al.
Journal of Applied Polymer Science, 44(4), 727-735 (1992)
Reactivity and regioselectivity in the Heck reaction: Hammett study of 4-substituted styrenes.
Fristrup P, et al.
Organometallics, 23(26), 6160-6165 (2004)
Formation of Bifunctional Octasilsesquioxanes via Silylative Coupling and Cross-Metathesis Reaction.
Małgorzata Bołt et al.
Materials (Basel, Switzerland), 13(18) (2020-09-12)
Bifunctional silsesquioxanes create an attractive group of compounds with a wide range of potential applications, and recently they have gained much interest. They are known to be obtained mainly via hydrosilylation, but we disclose novel synthetic protocols based on different
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