C102504
氧化环己烯
98%
别名:
1,2-环氧环己烷, 7-氧杂二环[4.1.0]庚烷
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关于此项目
经验公式（希尔记法）:
C6H10O
化学文摘社编号:
分子量:
98.14
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
206-007-7
Beilstein/REAXYS Number:
383568
MDL number:
InChI
1S/C6H10O/c1-2-4-6-5(3-1)7-6/h5-6H,1-4H2
InChI key
ZWAJLVLEBYIOTI-UHFFFAOYSA-N
SMILES string
C1CCC2OC2C1
assay
98%
form
liquid
autoignition temp.
703 °F
expl. lim.
12.36 %
refractive index
n20/D 1.452 (lit.)
bp
129-130 °C (lit.)
density
0.97 g/mL at 25 °C (lit.)
Quality Level
Application
- Polymeric carbon nitride with internal np homojunctions for efficient photocatalytic CO2 reduction coupled with cyclohexene oxidation：以氮化碳聚合物为催化剂，采用氧化环己烯进行CO2的光催化还原反应。CO2还原反应可解决环境问题，伴随的偶联反应可高效转化氧化环己烯(W Zhen et al., 2021)。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 1
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Donald J Darensbourg et al.
Journal of the American Chemical Society, 127(40), 14026-14038 (2005-10-06)
The mechanism of the copolymerization of cyclohexene oxide and carbon dioxide to afford poly(cyclohexylene)carbonate catalyzed by (salen)CrN3 (H2salen = N,N,'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylene-diimine) in the presence of a broad range of cocatalysts has been studied. We have previously established the rate of copolymer
Kathila S Rajapaksa et al.
Toxicological sciences : an official journal of the Society of Toxicology, 96(2), 327-334 (2007-01-06)
Ovarian follicle disruption in mice caused by 7,12-dimethylbenz[a]anthracene (DMBA) is attributed to its bioactivation by CYP1B1 to a 3,4-epoxide which is then hydrolyzed to form a 3,4-diol by microsomal epoxide hydrolase (mEH). Further epoxidation by CYP1A1 or 1B1 forms the
Alternating copolymerization of epoxides and cyclic anhydrides: an improved route to aliphatic polyesters.
Ryan C Jeske et al.
Journal of the American Chemical Society, 129(37), 11330-11331 (2007-08-29)
Dongliang Chang et al.
Chemical communications (Cambridge, England), (8)(8), 960-961 (2003-05-15)
Hydrolysis of N-benzyloxycarbonyl-3,4-epoxy-pyrrolidine and cyclohexene oxide with the epoxide hydrolase of Sphingomonas sp. HXN-200, respectively, gave the corresponding vicinal trans-diols in high ee and yield, representing the first example of enantioselective hydrolysis of a meso-epoxide with a bacterial epoxide hydrolase.
Youli Xiao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(12), 3668-3678 (2005-04-14)
The intramolecular dinuclear zinc complexes generated in situ from the reaction of multidentate semi-azacrown ether ligands with Et(2)Zn, followed by treatment with an alcohol additive, were found to promote the copolymerization of CO(2) and cyclohexene oxide (CHO) with completely alternating
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