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质量水平
方案
99%
表单
powder
mp
170-175 °C (lit.)
SMILES字符串
Nc1ccccc1O
InChI
1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2
InChI key
CDAWCLOXVUBKRW-UHFFFAOYSA-N
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应用
2-氨基苯酚可用于合成：
- 与β氨基醇在Pd/C-I2催化下通过氧化环羰基化反应合成2-噁唑烷酮衍生物。
- 与亚水杨基-4-氨基安替比林合成席夫碱过渡金属(II)配合物。
- 在富氧气氛、活性碳催化下与醛合成2-芳基苯并噁唑。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 2
闪点(°F)
334.4 °F - closed cup
闪点(°C)
168 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
Synthesis, spectroscopic characterization, redox, and biological screening studies of some Schiff base transition metal (II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol.
Raman N, et al.
Synth. React. Inorg. Met.-Org. Chem. , 31(7), 1249-1270 (2001)
Synthesis of 2-oxazolidinone catalyzed by palladium on charcoal: a novel and highly effective heterogeneous catalytic system for oxidative cyclocarbonylation of β -aminoalcohols and 2-aminophenol.
Li F and Xia C
J. Catal., 227(2), 542-546 (2004)
Ru Chen et al.
Organic & biomolecular chemistry, 9(22), 7675-7679 (2011-09-23)
A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)·H(2)O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate
Yuka Kawashita et al.
Organic letters, 5(20), 3713-3715 (2003-09-26)
[reaction: see text] 2-Arylbenzoxazoles were directly synthesized from substituted 2-aminophenols and aldehydes in the presence of activated carbon (Darco KB) in xylene under an oxygen atmosphere.
Ericsson D Coy et al.
Organic letters, 12(9), 1976-1979 (2010-03-27)
An efficient and facile synthesis of trans-dihydrobenzofurans has been accomplished from o-aminophenols and phenylpropenes via a novel (one-pot) diastereoselective Pd-catalyzed oxyarylation reaction. The development and optimization of this method is described.
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