96662
三己基十四烷化膦溴化物
≥95%
别名:
十四烷基三己基溴化膦
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关于此项目
线性分子式:
[CH3(CH2)5]3P(Br)(CH2)13CH3
化学文摘社编号:
分子量:
563.76
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
三己基十四烷化膦溴化物, ≥95%
InChI key
RJELOMHXBLDMDB-UHFFFAOYSA-M
SMILES string
[Br-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC
InChI
1S/C32H68P.BrH/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;/h5-32H2,1-4H3;1H/q+1;/p-1
assay
≥95%
≥95.0% (T)
form
solid
density
0.96 g/mL at 20 °C (lit.)
functional group
phosphine
Quality Level
Application
三己基十四烷化膦溴化物是一种膦基离子液体，可作为可循环利用的反应培养基，用于 Heck 交叉偶联反应。它也可用于制备支撑液膜（SLM），用于气体分离过程。
用于以下反应的反应物：
- 通过无溶剂阴离子复分解反应制备离子液体
- 制备钨磷酸盐四烷基膦和异钨酸林德奎斯特簇阴离子
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Gas separation properties of supported liquid membranes prepared with unconventional ionic liquids.
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Journal of Membrane Science, 349(1), 6-11 (2010)
Heck reactions of aryl halides in phosphonium salt ionic liquids: library screening and applications.
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Guokai Cui et al.
Chemistry, an Asian journal, 12(21), 2863-2872 (2017-08-26)
A new strategy involving the computer-assisted design of substituted imidazolate-based ionic liquids (ILs) through tuning the absorption enthalpy as well as the basicity of the ILs to improve SO
Francisco José Alguacil et al.
Scientific reports, 10(1), 13868-13868 (2020-08-19)
By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324H+Cl- was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables
Karolina Matuszek et al.
Molecules (Basel, Switzerland), 25(1) (2019-12-28)
Low solubility of terephthalic acid in common solvents makes its industrial production very difficult and not environmentally benign. Ionic liquids are known for their extraordinary solvent properties, with capability to dissolve a wide variety of materials, from common solvents to
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