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质量水平
检测方案
≥95%
≥95.0% (T)
形式
solid
密度
0.96 g/mL at 20 °C (lit.)
SMILES字符串
[Br-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC
InChI
1S/C32H68P.BrH/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;/h5-32H2,1-4H3;1H/q+1;/p-1
InChI key
RJELOMHXBLDMDB-UHFFFAOYSA-M
应用
三己基十四烷化膦溴化物是一种膦基离子液体，可作为可循环利用的反应培养基，用于 Heck 交叉偶联反应。它也可用于制备支撑液膜（SLM），用于气体分离过程。
用于以下反应的反应物：
- 通过无溶剂阴离子复分解反应制备离子液体
- 制备钨磷酸盐四烷基膦和异钨酸林德奎斯特簇阴离子
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Heck reactions of aryl halides in phosphonium salt ionic liquids: library screening and applications.
Gerritsma DA, et al.
Tetrahedron Letters, 45(41), 7629-7631 (2004)
Gas separation properties of supported liquid membranes prepared with unconventional ionic liquids.
Cserjesi P, et al.
Journal of Membrane Science, 349(1), 6-11 (2010)
Guokai Cui et al.
Chemistry, an Asian journal, 12(21), 2863-2872 (2017-08-26)
A new strategy involving the computer-assisted design of substituted imidazolate-based ionic liquids (ILs) through tuning the absorption enthalpy as well as the basicity of the ILs to improve SO
Francisco José Alguacil et al.
Scientific reports, 10(1), 13868-13868 (2020-08-19)
By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324H+Cl- was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables
Karolina Matuszek et al.
Molecules (Basel, Switzerland), 25(1) (2019-12-28)
Low solubility of terephthalic acid in common solvents makes its industrial production very difficult and not environmentally benign. Ionic liquids are known for their extraordinary solvent properties, with capability to dissolve a wide variety of materials, from common solvents to
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