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安全信息

935972

Sigma-Aldrich

Sodium hexafluorophosphate solution

new
greener alternative

in ethylene carbonate, dimethylcarbonate, and ethylmethylcarbonate, 1.0 M NaPF6 in EC/DMC/EMC=1:1:1 (v/v/v), battery grade

别名:

1.0 M NaPF6 in EC/DMC/EMC

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About This Item

CAS号:
MDL编号:
UNSPSC代码:
12352600

等级

battery grade

质量水平

表单

solution

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

浓度

0.95-1.10 M (NaPF6)

杂质

≤100 ppm Acid
≤100.0 ppm H2O

应用

battery manufacturing

环保替代产品分类

SMILES字符串

[Na+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1

InChI key

KMADQUOCJBLXRP-UHFFFAOYSA-N

相关类别

一般描述

Sodium hexafluorophosphate (NaPF6) solution in ethylene carbonate (EC), dimethylcarbonate (DMC), and ethylmethylcarbonate (EMC) is a clear solution of battery grade sodium hexafluorophosphate dissolved in a a ternary mixture of EC/DMC/EMC (1:1:1) (v/v/v). We offer this with a superior quality suitable for battery research with low water and acid impurities.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

应用

The main application of 1.0 M NaPF6 in EC/DMC/EMC=1:1:1 (v/v/v) is as an electrolyte in sodium-ion batteries (NIBs). The solvent blend has a high dielectric constant, which allows for effective dissolution of the electrolyte salt and results in high ionic conductivity. The fraction of ethylene carbonate (EC) helps to form a stable, conductive solid electrolyte interphase (SEI) with many cathode anode materials. Ethyl methyl carbonate (EMC) and dimethyl carbonate (DMC) have lower viscosities and melting points than EC, and when mixed with EC result in an electrolyte with a good balance between desirable electrochemical properties, high dielectric constant, and low viscosity. This electrolyte has been shown to have good electrochemical performance even at low temperatures, making it suitable for use in cold environments.

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 2 Oral

靶器官

Kidney

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

77.0 °F

闪点(°C)

25 °C

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Sodium-ion batteries: present and future
Hwang, Jang-Yeon
Chemical Society Reviews, 12 (2017)
Comparative study on the ionic conductivities and redox properties of LiPF6 and LiTFSI electrolytes and the characteristics of their rechargeable lithium ion batteries
Septiana, A. R.
IOP Conference Series: Materials Science and Engineering, 432 (2018)
A Study of the Physical Properties of Li-Ion Battery Electrolytes Containing Esters
Logan, E.R.
Journal of the Electrochemical Society, 165 (2018)

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