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Merck
CN

932760

Sigma-Aldrich

PTCDA

别名:

3,4,9,10-苝四甲酸二酐, Pigment Red 224

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About This Item

经验公式(希尔记法):
C24H8O6
CAS号:
分子量:
392.32
Beilstein:
57831
MDL编号:
UNSPSC代码:
12352103
NACRES:
NA.21

方案

99% (sublimed)

质量水平

mp

>300 °C

溶解性

DMSO: slightly soluble

轨道能量

HOMO 5.85 eV 
LUMO 3.9 eV 

SMILES字符串

O1C(=O)c2c3c4c(c5c6c(c4cc2)ccc7c6c(cc5)C(=O)OC7=O)ccc3C1=O

InChI

1S/C24H8O6/c25-21-13-5-1-9-10-2-6-15-20-16(24(28)30-23(15)27)8-4-12(18(10)20)11-3-7-14(22(26)29-21)19(13)17(9)11/h1-8H

InChI key

CLYVDMAATCIVBF-UHFFFAOYSA-N

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应用

3,4,9,10-Perylenetetracarboxylic dianhydride, also known as Perylenetetracarboxylic acid dianhydride, is a large π-conjugated semiconductor aromatic organic molecule. It is an organic dye molecule and an organic semiconductor. It is used as a precursor to a class of molecules known as Rylene dyes, which are useful as pigments and dyes. It is a dark red solid with low solubility in aromatic solvents.
The compound has attracted much interest as an organic semiconductor. It has potential applications in organic and molecular electronics, and typically used as an archetype molecular compound. PTCDA shares many properties with conventional semiconductors (with their delocalized electronic states), and insulator-like organic molecular crystals (OMCs) (with their large absorption oscillator strengths, excitonic self-trapping, polaron-assisted conduction, etc.). That is due to extremely close π-π stacking, an unusually small intermolecular distance of only 3.21 A. Among its applications, it is important to highlight the latest focus on environment monitoring, self-assembly and photocatalysis.

储存分类代码

11 - Combustible Solids

WGK

WGK 1


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Weiqin Wei et al.
Small (Weinheim an der Bergstrasse, Germany), 15(49), e1903933-e1903933 (2019-10-28)
A semi-core-shell structure of perylene diimide (PDI) self-assembly coated with TiO2 nanoparticles is constructed, in which nanoscale porous TiO2 shell is formed and PDI self-assembly presented 1D structure. A full-spectrum photocatalyst is obtained using this structure to resolve a conundrum-TiO2
Self-assembled perylene diimide based supramolecular heterojunction with Bi2WO6 for efficient visible-light-driven photocatalysis
Zhang, Kai, et al.
Applied Catalysis. B, Environmental, 232, 175-181 (2018)
Kangyi Kong et al.
Chemical communications (Cambridge, England), 55(56), 8090-8093 (2019-06-25)
In this communication, a self-assembled supramolecular system consisting of phosphoric acid substituted perylene diimide (P-PMPDI) has been successfully developed for highly efficient photocatalytic hydrogen evolution. Compared with a carboxylic substituent perylene diimide (P-CMPDI), P-PMPDI showed a superior H2 evolution reaction
Zijian Zhang et al.
Advanced materials (Deerfield Beach, Fla.), 32(32), e1907746-e1907746 (2020-07-01)
A highly crystalline perylene imide polymer (Urea-PDI) photocatalyst is successfully constructed. The Urea-PDI presents a wide spectrum response owing to its large conjugated system. The Urea-PDI performs so far highest oxygen evolution rate (3223.9 µmol g-1 h-1 ) without cocatalysts
Vibronic structure of PTCDA stacks: the exciton-phonon-charge-transfer dimer
Hennessy, M. H., et al.
Chemical Physics, 245, 199-212 (1999)

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