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  • A self-assembled perylene diimide nanobelt for efficient visible-light-driven photocatalytic H2 evolution.

A self-assembled perylene diimide nanobelt for efficient visible-light-driven photocatalytic H2 evolution.

Chemical communications (Cambridge, England) (2019-06-25)
Kangyi Kong, Shicong Zhang, Yanmeng Chu, Yue Hu, Fengtao Yu, Haonan Ye, Haoran Ding, Jianli Hua
摘要

In this communication, a self-assembled supramolecular system consisting of phosphoric acid substituted perylene diimide (P-PMPDI) has been successfully developed for highly efficient photocatalytic hydrogen evolution. Compared with a carboxylic substituent perylene diimide (P-CMPDI), P-PMPDI showed a superior H2 evolution reaction rate of 11.7 mmol g-1 h-1 and a recorded apparent quantum yield (AQY) of 2.96% at 550 nm.

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