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Merck
CN

932159

Sigma-Aldrich

t-DABNA

≥99% (HPLC)

别名:

2,12-Di-tert-butyl-5,9-bis(4-(tert-butyl)phenyl)-5,9-dihydro-5,9-diaza-13b-boranaphtho[3,2,1-de]anthracene

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About This Item

经验公式(希尔记法):
C46H53BN2
分子量:
644.74
MDL编号:
UNSPSC代码:
12352005
NACRES:
NA.23
方案:
≥99% (HPLC)
等级:
sublimed grade
溶解性:
methylene chloride: soluble

等级

sublimed grade

质量水平

方案

≥99% (HPLC)

带隙

2.7 eV, HOMO-LUMO gap

energy gap

0.17 eV, delta EST

转变温度

transition temp 418.7 °C (Td by TGA)

溶解性

methylene chloride: soluble

λmax

445 nm in dichloromethane

轨道能量

HOMO -5.72 eV 
LUMO -3.02 eV 

应用

Recent advancement in boron-based efficient and pure blue thermally activated delayed fluorescence materials for organic light emitting diodes. This is a sublimed high purity material, used as TADF Blue Dopant, with a EQE of 25.1%.
t-DABNA can be used as a host material or as a hole-blocking material in the emissive layer of OLED devices. Its high triplet energy level and other properties can contribute to efficient exciton management and improved device performance. It can also be used in studies on organic photovoltaic (OPV) devices and organic field-effect transistors (OFETs).

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Ideal blue thermally activated delayed fluorescent emission assisted by a thermally activated delayed fluorescent assistant dopant through a fast reverse intersystem crossing mediated cascade energy transfer process.
Han H S, et al.
Journal of Material Chemistry C, 7, 3082-3089 (2019)
Hyuna Lee et al.
Frontiers in chemistry, 8, 373-373 (2020-06-09)
In the last few years, electron-deficient materials have been actively researched for application in organic light-emitting diode (OLED) as dopant and electron-transporting materials. The boron-containing materials are interesting as they give good emissive properties in solid state with an electron-accepting

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