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Merck
CN

926396

Sigma-Aldrich

Solution-processable Blue TADF TB-P3Cz

≥95%

别名:

9′-(2,12-Di-tert-butyl-5,9-dioxa-13b-boranaphtho- [3,2,1-de]anthracen-7-yl)-9,9′′-diphenyl-9H,9′H,9′′H-3,3′:6′,3′′-tercarbazole, TADF Blue, TADF no host

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About This Item

经验公式(希尔记法):
C74H56BN3O2
分子量:
1030.07
MDL编号:
UNSPSC代码:
12352103
NACRES:
NA.23

描述

PL: 460 nm (film)


ΔEST : 0.113 eV

blue light

质量水平

方案

≥95%

表单

powder

颜色

yellow

溶解性

THF: soluble
dichloromethane: soluble
toluene: soluble

轨道能量

HOMO -4.88 eV 
LUMO -1.72 eV 

应用

Purely organic TADF emitters can recruit both singlet and triplet excitions for light emission and hence achieve 100% internal quantum efficiency (IQE). Additionally, purely organic TADF emitters avoid the problems associated with the use of heavy-metal-based organometallic complexes.
Bright, deep blue and stable emitters for OLEDs are grand challenge on OLED design at the moment. In this context, our TB-P3Cz is a promising TADF as solution-processable TADF blue emitter without the need of a host with a singlet–triplet energy gap (ΔEST) of 0.113 eV.
TADF blue materials can be investigated for their potential in organic light-emitting diodes (OLEDs). TADF emitters exhibit efficient utilization of both singlet and triplet excitons, resulting in enhanced device efficiency and reduced energy loss. It can is suitable in R&D studies of optoelectronic devices that require blue emission within the visible spectrum.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

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Color-Tunable Boron-Based Emitters Exhibiting Aggregation-Induced Emission and Thermally Activated Delayed Fluorescence for Efficient Solution-Processable Nondoped Deep-Blue to Sky-Blue OLEDs.
H.J. Kim et al.
Advanced Mat. (2020)
Highly efficient blue thermally activated delayed fluorescence organic light emitting diodes based on tercarbazole donor and boron acceptor dyads.
D.Karthik et al.,
Journal of Material Chemistry C, 8, 2272-2279 (2020)

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