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Merck
CN

926396

Sigma-Aldrich

Solution-processable Blue TADF TB-P3Cz

≥95%

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别名:
9′-(2,12-Di-tert-butyl-5,9-dioxa-13b-boranaphtho- [3,2,1-de]anthracen-7-yl)-9,9′′-diphenyl-9H,9′H,9′′H-3,3′:6′,3′′-tercarbazole, TADF Blue, TADF no host
经验公式(希尔记法):
C74H56BN3O2
分子量:
1030.07
NACRES:
NA.23

描述

PL: 460 nm (film)


ΔEST : 0.113 eV

blue light

质量水平

检测方案

≥95%

形式

powder

颜色

yellow

溶解性

THF: soluble
dichloromethane: soluble
toluene: soluble

轨道能量

HOMO -4.88 eV 
LUMO -1.72 eV 

应用

Purely organic TADF emitters can recruit both singlet and triplet excitions for light emission and hence achieve 100% internal quantum efficiency (IQE). Additionally, purely organic TADF emitters avoid the problems associated with the use of heavy-metal-based organometallic complexes.
Bright, deep blue and stable emitters for OLEDs are grand challenge on OLED design at the moment. In this context, our TB-P3Cz is a promising TADF as solution-processable TADF blue emitter without the need of a host with a singlet–triplet energy gap (ΔEST) of 0.113 eV.
TADF blue materials can be investigated for their potential in organic light-emitting diodes (OLEDs). TADF emitters exhibit efficient utilization of both singlet and triplet excitons, resulting in enhanced device efficiency and reduced energy loss. It can is suitable in R&D studies of optoelectronic devices that require blue emission within the visible spectrum.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Highly efficient blue thermally activated delayed fluorescence organic light emitting diodes based on tercarbazole donor and boron acceptor dyads.
D.Karthik et al.,
Journal of Material Chemistry C, 8, 2272-2279 (2020)
Color-Tunable Boron-Based Emitters Exhibiting Aggregation-Induced Emission and Thermally Activated Delayed Fluorescence for Efficient Solution-Processable Nondoped Deep-Blue to Sky-Blue OLEDs.
H.J. Kim et al.
Advanced Mat. (2020)

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