推荐产品
表单
solid
质量水平
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: ligand
标记范围
~1-1.5 mmol/g Capacity (Phosphor)
基质
crosslinked with 1% DVB
粒径
100-200 mesh
官能团
phosphine
储存温度
2-8°C
SMILES字符串
c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI
1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI key
RIOQSEWOXXDEQQ-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
Triphenylphosphine, polymer-bound is polystyrene crosslinked with divinylbenzene, widely used in many organic syntheses such as peptide synthesis, heterocycle synthesis, esterification, and total synthesis. It can be easily removed from the reaction products by simple filtration.
应用
Triphenylphosphine, polymer-bound is used as a polymer support to synthesize dipeptides, olefins, aryl-alkyl ethers, and in the esterification of alkylphosphonic acids. It acts as a Lewis acid, and dehydrating agent when complexed with halogen, hence useful in the acetonation of sugars.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Polymer-bound triphenylphosphine as traceless reagent for Mitsunobu reactions in combinatorial chemistry: Synthesis of aryl ethers from phenols and alcohols
Tetrahedron Letters, 48, 8751-8754 (1998)
Triphenylphosphine polymer-bound/iodine complex: A suitable reagent for the preparation of O-isopropylidene sugar derivatives
Synthesis, 2006, 305-308 (2006)
Synthesis of aryl ethers from aminoalcohols using polymer-supported triphenylphosphine
Tetrahedron Letters, 43, 2157-2159 (2002)
Mild and efficient esterification of alkylphosphonic acids using polymer-bound triphenylphosphine
Tetrahedron Letters, 53, 3795-3797 (2012)
Polymer-supported triphenylphosphine: application in organic synthesis and organometallic reactions
Royal Society of Chemistry Advances, 9 (2019)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门