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经验公式(希尔记法):
C6H12N2Si
化学文摘社编号:
分子量:
140.26
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-040-3
Beilstein/REAXYS Number:
606148
MDL number:
产品名称
1-(三甲基硅基)咪唑, ≥98.0%
InChI key
YKFRUJSEPGHZFJ-UHFFFAOYSA-N
InChI
1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
SMILES string
C[Si](C)(C)n1ccnc1
grade
synthesis grade
assay
≥98.0% (T)
≥98.0%
form
liquid
refractive index
n20/D 1.475 (lit.)
bp
93-94 °C/14 mmHg (lit.)
density
0.957 g/mL at 20 °C
0.956 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
1-(三甲基硅烷基)咪唑可作为 N 、 O -双(三甲基硅烷基)三氟乙酰胺 (BSTFA) 和 N -甲基- N -(三甲基硅烷基)三氟乙酰胺 (MSTFA) 的有效替代品,用于钛取代介孔分子筛 Ti-MCM-41 的有效硅烷化。该工艺提高了 Ti-MCM-41 催化剂的疏水性和催化活性。
Other Notes
高效硅烷化试剂,特别适合用于醇、酰基咪唑类的合成
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Silylation of Ti?MCM?41 by trimethylsilyl?imidazole and its effect on the olefin epoxidation with aqueous H 2 O 2.
Bu J & Rhee HK
Catalysis Letters, 66(4), 245-249 (2000)
Lukas Schmidt et al.
Archives of toxicology, 91(2), 677-687 (2015-12-19)
We studied the human in vivo metabolism and the elimination kinetics of α-pinene (αPN), a natural monoterpene which commonly occurs in the environment. Four volunteers were exposed to a single oral dose of 10 mg αPN. Each subject provided one pre-exposure
K. Blau et al.
Handbook of Derivatives for Chromatography (1993)
G.S. Bates et al.
Tetrahedron Letters, 4423-4423 (1976)
J.D. Nicholson
Analyst, 103, 193-193 (1978)
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