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Merck
CN
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文件

926132

Sigma-Aldrich

(R,R)-Ms-DENEB™

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别名:
stereoisomer of Chloro[N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]methanesulfonamidato-κN]ruthenium
经验公式（希尔记法）:
C25H29ClN2O3RuS
CAS号:
1333981-86-4
分子量:
574.10
NACRES:
NA.22

形式

powder

质量水平

100

反应适用性

reagent type: ligand

官能团

phosphine

相关类别

应用

(R,R)-Ms-DENEB™ is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

包装

Package under a dry inert gas.

其他说明

Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2 Hydrogenation

法律信息

Product of Takasago. For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.

相关产品

产品编号
说明
价格

926116

(R,R)-Ts-DENEB™

926140

(S,S)-Ms-DENEB™

926124

(S,S)-Ts-DENEB™

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high

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