所有图片(1)
About This Item
经验公式（希尔记法）:
C71H73ClN2O2P2Ru
CAS号:
分子量:
1184.82
MDL编号:
UNSPSC代码:
12352116
NACRES:
NA.22
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质量水平
表单
powder
反应适用性
reagent type: ligand
官能团
phosphine
SMILES字符串
[Ru+]c9c(ccc(c9)OC)C(N)([C@@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]
InChI key
VBDGCLWXZBVBHR-UCPQXOCLSA-M
应用
(S)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.
法律信息
Product of Takasago.
For research and development purposes only. PCT/JP2010/072838
For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.
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储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and
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