form
powder or crystals
mp
141-147 °C
Application
[Ru(η3:η3-C10H16)Cl(μ2-O,O-O2CMe)] is a ruthenium catalyst developed for the redox-neutral isomerization of allylic alcohols to saturated carbonyls under physiological conditions. This bioorthoganol and biocompatible catalyst has also been shown to be active inside living cells.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Nicolás Ríos-Lombardía et al.
Chemical communications (Cambridge, England), 51(54), 10937-10940 (2015-06-13)
The ruthenium-catalysed isomerisation of allylic alcohols was coupled, for the first time, with asymmetric bioamination in a one-pot process in an aqueous medium. In the cases involving prochiral ketones, the ω-TA exhibited excellent enantioselectivity, identical to that observed in the
Cristian Vidal et al.
Journal of the American Chemical Society, 141(13), 5125-5129 (2019-03-21)
Tailored ruthenium(IV) complexes can catalyze the isomerization of allylic alcohols into saturated carbonyl derivatives under physiologically relevant conditions, and even inside living mammalian cells. The reaction, which involves ruthenium-hydride intermediates, is bioorthogonal and biocompatible, and can be used for the
Nicolás Ríos-Lombardía et al.
Angewandte Chemie (International ed. in English), 55(30), 8691-8695 (2016-06-04)
The ruthenium-catalyzed redox isomerization of allylic alcohols was successfully coupled with the enantioselective enzymatic ketone reduction (mediated by KREDs) in a concurrent process in aqueous medium. The overall transformation, formally the asymmetric reduction of allylic alcohols, took place with excellent
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