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Merck
CN

911178

Sigma-Aldrich

PS-750-M

greener alternative

solution, 3 wt. % in H2O

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别名:
FI-750-M solution
线性分子式:
(C2H4O)nC18H33NO3
UNSPSC代码:
12352200
NACRES:
NA.22

形式

liquid

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

浓度

3 wt. % in H2O

折射率

n/D 1.3373

密度

0.9931 g/mL

环保替代产品分类

储存温度

2-8°C

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一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase catalytic efficiency and also acts as an environmentally benign and sustainable amphiphile. Click here for more information.

应用

PS-750-M 3% solution in water is a custom surfactant developed in the Handa lab.
PS-750-M allows for a variety of reactions, including challenging cross-couplings and monofluorination of indoles, to be conducted in water.

WGK

WGK 3


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Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions.
Brals J, et al.
ACS Catalysis, 7245-7250 (2017)
Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions.
Brals J, et al.
ACS Catalysis, 7(10), 7245-7250 (2017)
Pranjal P Bora et al.
ChemSusChem, 12(13), 3037-3042 (2019-03-06)
Highly selective direct monofluorination of indoles and arenes was developed through an approach that allows site-specific solubility of substrate and fluorine source in the micelle. This approach was highly selective for a broad range of substrates with excellent functional group
Lucie Finck et al.
The Journal of organic chemistry, 83(14), 7366-7372 (2018-02-10)
Using micelles of FI-750-M, visible light, photocatalysts, and inexpensive halogenating reagents, such as N-bromosuccinimide and N-chlorosuccinimde, selective oxyhalogenations of alkynes were achieved in water under very mild conditions. No halogenation at the aromatic rings was detected, and control experiments revealed

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