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检测方案
≥95%
形式
powder or crystals
反应适用性
reagent type: ligand
reaction type: Asymmetric synthesis
mp
226-228 °C
SMILES字符串
CC[C@@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2
应用
(R,R,R)-SPIRAP is a chiral C2-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Angewandte Chemie (International ed. in English), 57(19), 5325-5329 (2018-02-24)
We present an expedient and economical route to a new spiroketal-based C2 -symmetric chiral scaffold, termed SPIROL. Based on this spirocyclic scaffold, several chiral ligands were generated. These ligands were successfully employed in an array of stereoselective transformations, including in
Design, Synthesis, and Application of Chiral C2-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis.
Angewandte Chemie (International Edition in English), 57(19), 5325-5329 (2018)
相关内容
The Nagorny group has designed a new class of spiroketal-based chiral scaffolds termed SPIROLs. The SPIROL-based ligands have demonstrated excellent performance in a variety of Pd-, Rh- and Ir-catalyzed transformations while being easily accessible. Other focus areas are asymmetric catalysis, chiral catalyst, ligand design, which are all dedicated to the development of immobilized organic catalysts.
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