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905100

Sigma-Aldrich

Ir(p-tBu-ppy)3

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About This Item

经验公式（希尔记法）:
C45H48IrN3
CAS号:
1396451-04-9
分子量:
823.10
MDL编号:
MFCD31924979
UNSPSC代码:
12352101
NACRES:
NA.22

表单

powder

反应适用性

reaction type: Photocatalysis
reagent type: catalyst

SMILES字符串

[Ir](c5c(ccc(c5)C(C)(C)C)c6ncccc6)(c3c(ccc(c3)C(C)(C)C)c4ncccc4)c1c(ccc(c1)C(C)(C)C)c2ncccc2

InChI

1S/3C15H16N.Ir/c3*1-15(2,3)13-9-7-12(8-10-13)14-6-4-5-11-16-14;/h3*4-7,9-11H,1-3H3;

InChI key

HVSYDKXCADBJCU-UHFFFAOYSA-N

相关类别

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产品编号
说明
价格

688096

三[2-苯基吡啶-C2,N]铱(III), 97%

900540

Ir(dFppy)3

900539

铱 [ p -F (t-Bu)-ppy] 3

900538

Ir(p-F-ppy)3

900570

Ir[dF(t-Bu)-ppy]3

904694

Ir(p-CF3-ppy)3, ≥95%

905097

Ir(p-Me-ppy)3

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

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Eric D Nacsa et al.
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Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low
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Organic letters, 18(16), 3996-3999 (2016-08-06)
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ACS catalysis, 7(10), 7136-7140 (2017-11-08)
The development of synthetic methodologies which provide access to both stereoisomers of α,β-disubstituted olefins is a challenging undertaking. Herein, we describe the development of an operationally simple and stereoselective synthesis of difluoromethylated styrenes via a visible-light photocatalytic decarboxylation strategy using
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Journal of Organometallic Chemistry, 776, 51-59 (2015)

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