904767
[Ru(phen)3]Cl2
≥95%, powder or crystals
别名:
氯化二氯三（1,10-菲咯啉）钌（II）
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关于此项目
经验公式（希尔记法）:
C36H24Cl2N6Ru
化学文摘社编号:
分子量:
712.59
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
产品名称
[Ru(phen)3]Cl2, ≥95%
SMILES string
[Ru+2]951([NH]%10=C%11C%12=[NH]9C=CC=C%12C=CC%11=CC=C%10)([NH]6=C7C8=[NH]5C=CC=C8C=CC7=CC=C6)[NH]2=C3C4=[NH]1C=CC=C4C=CC3=CC=C2.[Cl-].[Cl-]
InChI
1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2
InChI key
UWXWBVKIJZGXQL-UHFFFAOYSA-L
assay
≥95%
form
powder or crystals
reaction suitability
core: ruthenium
reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
Application
Other Notes
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Tanmay Chatterjee et al.
The Journal of organic chemistry, 81(16), 6995-7000 (2016-06-22)
A simple and practical method for the synthesis of substituted oxazoles has been developed using readily available α-bromoketones and benzylamines by visible-light photocatalysis at room temperature. The process, which requires 1 mol % of [Ru(bpy)3]Cl2 photocatalyst with K3PO4 and CCl3Br
Jun Chen et al.
Chemical communications (Cambridge, England), 54(50), 6780-6783 (2018-02-06)
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished, providing a mild and efficient approach to various functionalized isoxazolidines. The success of this protocol is based on the strategy of oxidative deprotonation
Adam Noble et al.
Angewandte Chemie (International ed. in English), 57(8), 2155-2159 (2018-01-10)
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the
Chelsea A Huff et al.
The Journal of organic chemistry, 81(16), 6980-6987 (2016-06-18)
We report the development of a method for room-temperature C-H hydroxymethylation of heteroarenes. A key enabling advance in this work was achieved by implementing visible light photoredox catalysis that proved to be applicable to many classes of heteroarenes and tolerant
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