754730
三（2,2′-联吡啶）钌（II）六氟磷酸盐
97%
别名:
Ru(bpy)3(PF6)2, 钌-三（2,2′-联吡啶）二六氟磷酸盐
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关于此项目
经验公式（希尔记法）:
C30H24F12N6P2Ru
化学文摘社编号:
分子量:
859.55
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
三（2,2′-联吡啶）钌（II）六氟磷酸盐, 97%
form
solid
InChI
1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2
SMILES string
[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6
InChI key
KLDYQWXVZLHTKT-UHFFFAOYSA-N
description
Emissive Layer
assay
97%
reaction suitability
core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst
impurities
(Material is not fluorescence active.)
mp
>300 °C
photocatalyst activation
425 nm
absorption
13,400 at 456 nm
80,000 at 291 nm
Quality Level
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
Buda, M
Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
Single layer light-emitting devices with high efficiency and long lifetime based on tris (2, 2? bipyridyl) ruthenium (II) hexafluorophosphate
Rudmann H and Rubner MF
Journal of Applied Physics, 90(9), 4338-4345 (2001)
Wesley R Browne et al.
Journal of the American Chemical Society, 125(7), 1706-1707 (2003-02-13)
The excited-state properties of the transition metal complexes tris(2,2'-bipyridine) ruthenium(II) and tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) are examined using picosecond time-resolved luminescence spectroscopy. For both complexes, direct observation of a short-lived high-energy emission with a lifetime of less than 4 ps is reported.
Silvia Voci et al.
Analytical and bioanalytical chemistry, 412(17), 4067-4075 (2020-04-29)
Nanofluidic electrochemical devices confine the volume of chemical reactions to femtoliters. When employed for light generation by electrochemiluminescence (ECL), nanofluidic confinement yields enhanced intensity and robust luminescence. Here, we investigate different ECL pathways, namely coreactant and annihilation ECL in a
Valentina Leandri et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(4), 618-626 (2019-01-10)
The excited state dynamics of Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, [Ru(bpy)3 (PF6 )2 ], was investigated on the surface of bare and sensitized TiO2 and ZrO2 films. The organic dyes LEG4 and MKA253 were selected as sensitizers. A Stern-Volmer plot of LEG4-sensitized TiO2
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