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Merck
CN

901907

2-二环己基磷-2′,6′-二异丙氧基-1,1′-联苯

greener alternative

95%, powder or crystals

别名:

RuPhos

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关于此项目

经验公式（希尔记法）:
C30H43O2P
化学文摘社编号:
787618-22-8
分子量:
466.64
NACRES:
NA.22
UNSPSC Code:
12352112
MDL number:
MFCD06798294

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产品名称

2-二环己基磷-2′,6′-二异丙氧基-1,1′-联苯, 95%

InChI

1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3

SMILES string

CC(C)Oc1cccc(OC(C)C)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4

InChI key

MXFYYFVVIIWKFE-UHFFFAOYSA-N

assay

95%

form

powder or crystals

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

123-126 °C
125 °C

functional group

phosphine

greener alternative category

Aligned

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相关类别

Application

用于氨基乙基三氟硼酸酯与贫电子芳基溴化物的钯催化交叉偶联的块状膦配体。

Legal Information

专利使用：EP 1097158；JP 5758844；CA 2336691

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product has been enhanced for catalysis. Click here for more information.

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
WXBF5312V
WXBD0716V
WXBC7954V

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Paul Chatelain et al.
Angewandte Chemie (International ed. in English), 58(42), 14959-14963 (2019-08-24)
Ideal organic syntheses involve the rapid construction of C-C bonds, with minimal use of functional group interconversions. The Suzuki-Miyaura cross-coupling (SMC) is a powerful way to form biaryl linkages, but the relatively similar reactivity of electrophilic partners makes iterative syntheses

商品

1-tBu-Indenyl Supported Palladium Precatalysts for Cross-Coupling

The Hazari group has developed an improved palladium precatalyst scaffold for a wide range of cross-coupling reactions

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