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901062

Pinacol (dichloromethyl) boronate

Name: Pinacol (dichloromethyl) boronate
Brand: ALDRICH

≥95%

别名:

1,3,2-Dioxaborolane, 2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Dichloromethyl pinacol boronate

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About This Item

经验公式（希尔记法）:

C₇H₁₃BCl₂O₂

CAS号:

83622-41-7

分子量:

210.89

MDL编号:

MFCD27976342

UNSPSC代码:

12352200

NACRES:

NA.22

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质量水平

100

方案

≥95%

表单

(Powder or Solid or Crystals or Semi-Solid or Liquid)

折射率

n/D 1.4511

密度

1.1423

官能团

chloro

SMILES字符串

B1(OC(C(O1)(C)C)(C)C)C(Cl)Cl

InChI

1S/C7H13BCl2O2/c1-6(2)7(3,4)12-8(11-6)5(9)10/h5H,1-4H3

InChI key

GQFQFYFLABSDDS-UHFFFAOYSA-N

应用

Pinacol (dichloromethyl) boronate is a general reagent that was employed by Prof. Greg C. Fu and coworkers to achieve the iterative synthesis of asymmetric (secondary) alkyl boronate esters. These can be further derivatized through a growing suite of chemical transformations developed in the last decade (cross coupling, oxidation, amination, halogenation) that proceed with stereochemical fidelity.