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Merck
CN
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文件

安全信息

900989

Sigma-Aldrich

1,3,5-Phenyltriboronic acid, tris(pinacol) ester

≥97%

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别名:
1,3,5-Tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
经验公式（希尔记法）:
C24H39B3O6
CAS号:
365564-05-2
分子量:
456.00
MDL编号:
MFCD17167305
UNSPSC代码:
12352106
NACRES:
NA.06

质量水平

100

检测方案

≥97%

形式

powder or crystals

mp

286-287 °C

SMILES字符串

CC1(C)OB(OC1(C)C)C2=CC(B3OC(C)(C)C(C)(C)O3)=CC(B4OC(C)(C)C(C)(C)O4)=C2

InChI

1S/C24H39B3O6/c1-19(2)20(3,4)29-25(28-19)16-13-17(26-30-21(5,6)22(7,8)31-26)15-18(14-16)27-32-23(9,10)24(11,12)33-27/h13-15H,1-12H3

InChI key

VKOLBYNBPONPAE-UHFFFAOYSA-N

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相关类别

应用

1,3,5-Phenyltriboronic acid, tris(pinacol) ester can undergo Suzuki–Miyaura cross-coupling polycondensation reaction with 4,7-dibromobenzo[c][1,2,5]thiadiazole to afford conjugated polybenzothiadiazoles. It may also be used as a crosslinker for synthesizing conjugated microporous polymer (CMP) nanoparticles. This product was previously listed as BML00299.

其他说明

Molecular engineering of conjugated polybenzothiadiazoles for enhanced hydrogen production by photosynthesis

Conjugated microporous polymer nanoparticles with enhanced dispersibility and water compatibility for photocatalytic applications

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Conjugated microporous polymer nanoparticles with enhanced dispersibility and water compatibility for photocatalytic applications.
Ma BC, et al.
Journal of Material Chemistry A, 3, 16064-16071 (2015)
Can Yang et al.
Angewandte Chemie (International ed. in English), 55(32), 9202-9206 (2016-06-16)
The search for metal-free organic photocatalysts for H2 production from water using visible light remains a key challenge. Reported herein is a molecular structural design of pure organic photocatalysts, derived from conjugated polybenzothiadiazoles, for photocatalytic H2 evolution using visible light.

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