所有图片(1)
别名:
8-[2-[Bis(2-methylphenyl)phosphino]phenyl]-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
经验公式（希尔记法）:
C30H34O3P2
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质量水平
检测方案
95%
形式
powder or crystals
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
官能团
phosphine
应用
PAd-DalPhos is a versatile air stable pre-catalyst for C(sp2)-N coupling. It catalyzes N-arylation of amides with (hetero)aryl (pseudo)halide. It can also be used in the synthesis of unsymmetrical 1,3-di(hetero)aryl-1H-indazoles from hydrazine, o-chloro (hetero)benzophenones and (hetero)aryl bromides.
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Nickel?Catalyzed N?Arylation of Primary Amides and Lactams with Activated (Hetero) aryl Electrophiles.
Lavoie C M, et al.
Chemistry?A European Journal , 22(52), 18752-18755 (2016)
Ni and Cu-catalyzed one pot synthesis of unsymmetrical 1, 3-di (hetero) aryl-1H-indazoles from hydrazine, o-chloro (hetero) benzophenones, and (hetero) aryl bromides.
Wiethan C, et al.
Organic & Biomolecular Chemistry, 15(23), 5062-5069 (2017)
Christopher M Lavoie et al.
Nature communications, 7, 11073-11073 (2016-03-24)
Palladium-catalysed C(sp(2))-N cross-coupling (that is, Buchwald-Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical industry, for the synthesis of (hetero)aniline derivatives. However, the cost and relative scarcity of palladium provides motivation for the development of alternative, more
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