一般描述
- 一种稳定的三硫代碳酸酯链转移剂(CTA),也称为RAFT剂,可用于控制自由基聚合中的链增长,产生具有明确分子量和低多分散性的聚合物。
- 2-(2-十二烷基三硫代碳酸酯基)丙酸可用于控制丙烯酸、丙烯酸酯、丙烯酰胺、苯乙烯、甲基丙烯酸酯和甲基丙烯酰胺的均聚和共聚。它可溶于水性和有机介质(两亲性)。
注意
储存条件:室温,避光。
法律信息
仅限研究用途使用:参见 sigma-aldrich.com/raftlicense。专利:WO98/01478, WO99/311444。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Synthesis of Dual-Functional Poly(6-azidohexylmethacrylate) Brushes by a RAFT Agent Carrying Carboxylic Acid End Groups.
Journal of Polymer Science Part A: Polymer Chemistry, 53, 1696-1706 (2015)
Synthesis and Evaluation of New Dicarboxylic Acid Functional Trithiocarbonates: RAFT Synthesis of Telechelic Poly(n-butyl acrylate)s.
Macromolecules, 38, 9518-9525 (2005)
Substituent Effects on Trithiocarbonates-Mediated Polymerization of Styrene.
Journal of Applied Polymer Science, 111, 2011-2017 (2009)
Thermo-responsive shell cross-linked PMMA-b-P(NIPAAm-co-NAS) micelles for drug delivery.
International Journal of Pharmaceutics, 420(2), 333-340 (2011)
A Continuous Flow Process for the Radical Induced End Group Removal of RAFT Polymers.
Macromolecular Reaction Engineering, 6, 246-251 (2012)
商品
Low-cost, high-purity RAFT Agents are vital for industrial RAFT polymerization. We supply effective agents for this technology.
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