900152
2-[[(2-羧乙基)硫烷基硫代羰基]-硫烷基]丙酸
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关于此项目
经验公式（希尔记法）:
C7H10O4S3
化学文摘社编号:
分子量:
254.35
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.23
MDL number:
Quality Level
SMILES string
S(C(C)C(=O)O)C(=S)SCCC(=O)O
InChI key
IKWGMGMZWODWEO-UHFFFAOYSA-N
assay
95% (GC)
form
powder
mp
120-125 °C
Disclaimer
储存条件：室温，避光。
General description
- 一种稳定的三硫代碳酸酯链转移剂（CTA），也称为RAFT剂，可用于控制自由基聚合中的链增长，产生具有明确分子量和低多分散性的聚合物。
- 2-(2-十二烷基三硫代碳酸酯基)丙酸可用于控制丙烯酸、丙烯酸酯、丙烯酰胺、苯乙烯、甲基丙烯酸酯和甲基丙烯酰胺的均聚和共聚。它可溶于水性和有机介质（两亲性）。
Legal Information
仅限研究用途使用：参见 sigma-aldrich.com/raftlicense。专利：WO98/01478, WO99/311444。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Scale-up of the Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization Using Continuous Flow Processing.
Micic N, et al.
Processes, 2, 58-70 (2014)
Synthesis and Evaluation of New Dicarboxylic Acid Functional Trithiocarbonates: RAFT Synthesis of Telechelic Poly(n-butyl acrylate)s.
Wang R, et al.
Macromolecules, 38, 9518-9525 (2005)
Synthesis of Dual-Functional Poly(6-azidohexylmethacrylate) Brushes by a RAFT Agent Carrying Carboxylic Acid End Groups.
Cimen D, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 53, 1696-1706 (2015)
Thermo-responsive shell cross-linked PMMA-b-P(NIPAAm-co-NAS) micelles for drug delivery.
Chang C, et al.
International Journal of Pharmaceutics, 420(2), 333-340 (2011)
A Continuous Flow Process for the Radical Induced End Group Removal of RAFT Polymers.
Hornung H, et al.
Macromolecular Reaction Engineering, 6, 246-251 (2012)
商品
The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.
Low-cost, high-purity RAFT Agents are vital for industrial RAFT polymerization. We supply effective agents for this technology.
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