86890
四丁基碘化铵
≥99.0% (AT), crystals
别名:
TBAI
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(I)
化学文摘社编号:
分子量:
369.37
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
EC Number:
206-220-5
MDL number:
Beilstein/REAXYS Number:
3916152
产品名称
四丁基碘化铵, ≥99.0% (AT)
Quality Level
InChI key
DPKBAXPHAYBPRL-UHFFFAOYSA-M
InChI
1S/C16H36N.HI/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
SMILES string
[I-].CCCC[N+](CCCC)(CCCC)CCCC
assay
≥99.0% (AT)
form
crystals
mp
141-143 °C (lit.)
reaction suitability
core: ammonium
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General description
碘化四丁基铵是一种用于相转移反应的季铵盐。也用于区域选择醚裂解反应，可作为碘化物的来源进行亲核置换反应。
Application
碘化四丁基铵可用于：
- 作为添加剂，以钯为催化剂合成熔融三唑衍生物。
- 制备烯丙基-PEG-烯丙基，后者是合成含氟两亲性共聚物的关键中间体聚合物。
- 用作合成醚的催化剂。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 2
ppe
dust mask type N95 (US), Eyeshields, Gloves
flash_point_f
No data available
flash_point_c
No data available
S. Czernecki et al.
Tetrahedron Letters, 3535-3535 (1976)
J.M. Chong et al.
The Journal of Organic Chemistry, 52, 2596-2596 (1987)
R Bryan Sears et al.
Journal of inorganic biochemistry, 121, 77-87 (2013-01-29)
The complex cis-[Ru(phpy)(phen)(CH3CN)2](+) (phpy=2-phenylpyridine, phen=1,10-phenanthroline) was investigated as a potential photodynamic therapy (PDT) agent. This complex presents desirable photochemical characteristics including a low energy absorption tail extending into the PDT window (600-850nm) and photoinduced exchange of the CH3CN ligands, generating
Mei Shen et al.
Journal of the American Chemical Society, 134(24), 9856-9859 (2012-06-05)
Here we report on the unprecedentedly high resolution imaging of ion transport through single nanopores by scanning electrochemical microscopy (SECM). The quantitative SECM image of single nanopores allows for the determination of their structural properties, including their density, shape, and
Fabio Galeotti et al.
Journal of chromatography. A, 1284, 141-147 (2013-03-05)
In this study, by using tetrabutylammonium bisulfate as ion-pairing reagent, we were able to separate all the main heparin/heparan sulfate disaccharides generated by the action of heparinases along with the main Hep tetrasaccharide possessing a 3-O-sulfate group on the sulfoglucosamine
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