86870
四丁基氯化铵
≥97.0% (NT), crystals
别名:
N,N,N-tributyl-butanaminium chloride
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关于此项目
线性分子式:
[CH3(CH2)3]4NCl
化学文摘社编号:
分子量:
277.92
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
EC Number:
214-195-7
MDL number:
Beilstein/REAXYS Number:
3571227
产品名称
四丁基氯化铵, ≥97.0% (NT)
InChI key
NHGXDBSUJJNIRV-UHFFFAOYSA-M
InChI
1S/C16H36N.ClH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
SMILES string
[Cl-].CCCC[N+](CCCC)(CCCC)CCCC
assay
≥97.0% (NT)
form
crystals
greener alternative product characteristics
Catalysis
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sustainability
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impurities
≤1% water
solubility
H2O: 20 mg/mL, clear, colorless
greener alternative category
, Aligned
Quality Level
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Application
四丁基氯化铵 (TBACl) 可用作相转移催化剂用于合成：
TBACl 还可被用于与五氧化二磷一起用于更绿色的脱氧氯化反应。
Pr制备卤代杂芳基化合物。
- 2-氨基-4H-色烯衍生物，通过醛、丙二腈 和 α或 β-萘酚缩合反应制备。
- 甲酯，通过羧酸和碳酸二甲酯在K2CO3参与下的酯化反应生成。
TBACl 还可被用于与五氧化二磷一起用于更绿色的脱氧氯化反应。
Pr制备卤代杂芳基化合物。
General description
四丁基氯化铵是一种季铵盐，通常用作相转移催化剂以及有机合成中的氯离子源。
我们致力于为您带来更环保的替代产品，以符合绿色化学 12 项原则的一项或多项原则要求该产品为增强型，提高了能源效率。点击此处，查看更多详情。
我们致力于为您带来更环保的替代产品，以符合绿色化学 12 项原则的一项或多项原则要求该产品为增强型，提高了能源效率。点击此处，查看更多详情。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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The present study describes the synthesis of the first phenoxycalix[4]pyrrole-epichlorohydrin based polymer. The advantage of the latter resides in its fast-single step synthesis protocol, low cost, water insolubility and its unexpected anion extraction capacity. The study of this polymer by
Tetrabutylammonium Chloride-Induced Cascade Radical Addition/Cyclization of O-Isocyanodiaryl Amines: A Novel Protocol for the Synthesis of 11-Trifluoromethylated Dibenzodiazepines
Yuan S, et al.
The Journal of Organic Chemistry, 87, 16542-16549 (2022)
Efficient and eco-friendly synthesis of 2-amino-4H-chromene derivatives using catalytic amount of tetrabutylammonium chloride (TBAC) in water and solvent-free conditions
Mehrabi H and Kamali N
Journal of the Iranian Chemical Society, 9, 599-605 (2012)
Methyl esterification of carboxylic acids with dimethyl carbonate promoted by K2CO3/tetrabutylammonium chloride
Chau K, et al.
Green Chemistry Letters and Reviews, 6, 89-93 (2013)
I P E Macário et al.
Scientific reports, 9(1), 3932-3932 (2019-03-10)
The tailor-made character of deep eutectic solvents (DES) turns them very attractive to be used in several applications, including in health-related areas such as pharmaceutical, nutraceutical, and cosmetic industries. However, although DES has been touted as "green" solvents, several works
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