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Merck
CN

805394

FK 209 Co(III) TFSI salt

别名:

三(2-(1H-吡唑-1-基)-4-叔丁基吡啶)钴(III)三[双(三氟甲烷)磺酰亚胺]

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关于此项目

经验公式（希尔记法）:
C42H45CoF18O12N12S6
分子量:
1503.17
UNSPSC Code:
12352103
PubChem Substance ID:
329768935
NACRES:
NA.23

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InChI key

PZTBQPSYUSXHSB-UHFFFAOYSA-N

SMILES string

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.CC(C)(C)C1=CC(N2N=CC=C2)=NC=C1.CC(C)(C)C3=CC=NC(N4C=CC=N4)=C3.CC(C)(C)C5=CC=NC(N6C=CC=N6)=C5.C

assay

98%

form

powder

mp

281.5 °C (exp.)

Quality Level

100

相关类别

Application

FK 209可用于诱导PCDTBT和spiro-OMeTAD的p型掺杂，用于制造效率达15-16%的钙钛矿太阳能电池(PSC)的空穴传输材料。
用这种钴配合物大幅度提高液体电解质电池的光电压，或通过固态光伏器件实现超高性能。

General description

FK 209 Co(III) TFSI盐(FK 209)是一种钴(III)配合物，可以用作空穴传输材料用p型掺杂剂，使功率转换效率达9-12%。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ2955
MKCX1765
MKCS4988
MKCQ8807
MKCM9739

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Acid additives enhancing the conductivity of spiro-OMeTAD toward high-efficiency and hysteresis-less planar perovskite solar cells.
Li Z, et al.
Advanced Energy Materials, 7, 15714-15723 (2016)
Efficient perovskite photovoltaic devices using chemically doped PCDTBT as a hole-transport material.
Wong-Stringer M, et al.
Journal of Material Chemistry A, 5(30), 15714-15723 (2017)
Co (III) complexes as p-dopants in solid-state dye-sensitized solar cells
Burschka J, et al.
Chemistry of Materials, 25(15), 2986-2990 (2013)
Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
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