778583
叠氮苯 溶液
~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
别名:
苯基叠氮化物 溶液
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关于此项目
经验公式（希尔记法）:
C6H5N3
化学文摘社编号:
分子量:
119.12
Beilstein:
742248
MDL编号:
UNSPSC代码:
12352200
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥95.0% (HPLC)
表单
liquid
环保替代产品特性
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
浓度
~0.5 M in 2-methyltetrahydrofuran
杂质
≤2.0% water
环保替代产品分类
储存温度
−20°C
SMILES字符串
[N-]=[N+]=Nc1ccccc1
InChI
1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H
InChI key
CTRLRINCMYICJO-UHFFFAOYSA-N
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一般描述
Azidobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
应用
Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
10.4 °F
闪点(°C)
-12 °C
法规信息
危险化学品
此项目有
Pascal Viel et al.
Langmuir : the ACS journal of surfaces and colloids, 29(6), 2075-2082 (2013-01-16)
Covalent immobilization of unmodified biological materials as proteins has been performed through a one-step and soft method. This process is based on a polyazidophenylene layer derived from the electroreduction of the parent salt 4-azidobenzenediazonium tetrafluoborate on gold substrates. The wavelength
C Malaveille et al.
Cancer research, 42(4), 1446-1453 (1982-04-01)
3-Methyl-1-phenyltriazene and a series of ring-substituted derivatives (4-methylphenyl, 4-chlorophenyl, and 2,4,6-trichlorophenyl), structurally related benzenediazonium fluoborates and phenyl azides, as well as the recently isolated [1-methyl-3-(2,4,6-trichlorophenyl)-2-triazeno]methyl-beta-D-glucopyranoside uronic acid, were studied for their mutagenic activity in Salmonella typhimurium strains. Of these compounds
Laëtitia Renaudie et al.
Biomacromolecules, 8(2), 679-685 (2007-02-13)
Grafting of a new carbohydrate UV-reactive molecule, an azidophenyl lactamine (AzPhLac), was achieved on fibers of three different diameters: 12, 18, and 32 microm. Adsorption of AzPhLac on fibers was obtained by using the dip-coating method in solution. The effect
Solvent effects on the folding of o-phenylene oligomers
Vemuri GN, et al.
Organic & Biomolecular Chemistry, 15(4), 845-851 (2017)
Sameer A Al-Bataineh et al.
Langmuir : the ACS journal of surfaces and colloids, 25(13), 7432-7437 (2009-07-01)
N-(3-trimethoxysilylpropyl)-4-azido-2,3,5,6-tetrafluorobenzamide (PFPA-silane) was used as a photoactive cross-linker to immobilize antibacterial furanone molecules on silicon oxide surfaces. This immobilization strategy is useful, especially for substrates and molecules that lack reactive functional groups. To this end, cleaned wafers were initially incubated
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