所有图片(1)
别名:
1-Methylethylmagnesium bromide, 2-Propylmagnesium bromide, iso-Propylmagnesium bromide, Bromoisopropylmagnesium
线性分子式:
(CH3)2MgBr
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形式
solution
质量水平
反应适用性
reaction type: Grignard Reaction
浓度
0.75 M in THF
密度
0.982 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
CC(C)[Mg]Br
InChI
1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChI key
UCJIVFREPMUZDC-UHFFFAOYSA-M
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应用
- Preparation of isopropylmagnesium bromide solutions: In this study, various concentrations of isopropylmagnesium bromide solutions were prepared, detailing their stability and reactivity for use in palladium-catalyzed cross-coupling reactions and other synthetic applications (Vulović et al., 2017).
- Reductive coupling of amides: This research discusses the reductive functionalization of tertiary amides using isopropylmagnesium bromide, providing a novel method for amine synthesis, which is crucial for pharmaceutical chemistry (Xie and Dixon, 2017).
- Synthesis of 1, 2, 3-triazoles: The study explores the use of isopropylmagnesium bromide in the synthesis of 1, 2, 3-triazoles through Grignard reactions, highlighting its role in protecting azides during the reaction process (Namioka et al., 2023).
- Disposable cartridge concept for Grignard reagents: This paper introduces a novel disposable cartridge for the on-demand synthesis of Grignard reagents, including isopropylmagnesium bromide, enhancing the safety and scalability of Grignard reactions (Berton et al., 2020).
包装
建议将 25 mL Sure/Seal™ 瓶作为一次性瓶使用。重复穿刺可能会导致产品性能下降。
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Respiratory system
补充剂危害
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
危险化学品
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