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Merck
CN

768464

Sigma-Aldrich

2,7-二己基苯并[lmn][3,8]菲咯啉-1,3,6,8(2H,7H)-四酮

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别名:
N,N′-(1-己基)-1,4,5,8-萘四甲酰二亚胺, NDI-C6
经验公式(希尔记法):
C26H30N2O4
CAS号:
分子量:
434.53
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

检测方案

≥97.6%

形式

powder

mp

205-210 °C

λmax

380, 360, 342 nm in dichloromethane (lit.)

半导体性质

N-type (mobility=0.7 cm2/V·s)

SMILES字符串

CCCCCCN1C(=O)c2ccc3C(=O)N(CCCCCC)C(=O)c4ccc(C1=O)c2c34

InChI

1S/C26H30N2O4/c1-3-5-7-9-15-27-23(29)17-11-13-19-22-20(14-12-18(21(17)22)24(27)30)26(32)28(25(19)31)16-10-8-6-4-2/h11-14H,3-10,15-16H2,1-2H3

InChI key

QGDZMDFMUJURJD-UHFFFAOYSA-N

一般描述

2,7-二己基苯并[lmn][3,8]菲咯啉-1,3,6,8(2H,7H)-四酮是一种低分子量苝系衍生物,可用作场效应晶体管(FET)中的n型有机半导体。 它们具有高电子移动性和优异的开关电流比,即使在存在空气的情况下。此外,它们还具有良好的机械性能和耐化学性,耐各种溶剂。

应用

在有机印刷电子中用作n型半导体材料。

特点和优势

良好的热稳定性和低电子注入能障当从各向同性相冷却时,它们表现为近晶相,并且介晶在层内呈柱状排列。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Xiaowei Zhan et al.
Advanced materials (Deerfield Beach, Fla.), 23(2), 268-284 (2010-12-15)
Organic electron-transporting materials are essential for the fabrication of organic p-n junctions, photovoltaic cells, n-channel field-effect transistors, and complementary logic circuits. Rylene diimides are a robust, versatile class of polycyclic aromatic electron-transport materials with excellent thermal and oxidative stability, high
Wholly aromatic ether-imides. Potential materials for n-type semiconductors.
Dingemans, T. J., Picken, S. J., Murthy, N. S., Mark, P., StClair, T. L., & Samulski, E. T.
Chemistry of Materials, 16(6), 966-974 (2004)
Development of small molecule donors for solution-processed organic solar cells
Payne, A. J., & Welch, G. C.
Material Matters, 9(1), 23-32 (2014)

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