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Merck
CN
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文件

761435

Sigma-Aldrich

[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯

95%

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别名:
[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II) 甲磺酸酯, cataCXium-A-Pd-G3, 甲磺酸[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)
经验公式（希尔记法）:
C37H52NO3PPdS
CAS号:
1651823-59-4
分子量:
728.27
UNSPSC代码:
12352300
PubChem化学物质编号:
329766937
NACRES:
NA.22

质量水平

100

检测方案

95%

形式

solid

特点

generation 3

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

杂质

≤3% acetone

mp

196-241 °C (decomposition)

官能团

phosphine

SMILES字符串

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

InChI

1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;

InChI key

REYVZCOGMIXVNX-DVBMAMJVSA-M

相关类别

应用

cataCXium® A Pd G3 是一种第三代Buchwald预催化剂，可用于：
  • 吡啶羧酸的直接邻位芳基化。
  • 催化Suzuki–Miyaura交叉偶联反应，以合成1-杂芳基-3-氮杂双环[3.1.0]己烷。
  • 炔烃的钯催化羰基碳全氟烷基化。
  • 各种 gem二取代环丙烷的合成过程中成对二(溴基)环丙烷的Suzuki–Miyaura 偶联反应。
  • 末端炔烃的溴全氟烷基化。
  • 芳香卤化物和炔烃的无铜Sonogashira 偶联反应，以形成 C-C键。
  • 有机三氟硼酸盐和芳基卤化物的Suzuki 交叉偶联反应。
对于小规模和高通量用途，产品为ChemBeads ChemBeads (928305)

法律信息

cataCXium is a registered trademark of Umicore AG & Co. KG

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

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Copper-free Sonogashira cross-coupling reactions: an overview
Mohajer F, et al.
Royal Society of Chemistry Advances, 11, 6885-6925 (2021)
Construction of 1-Heteroaryl-3-azabicyclo [3.1. 0] hexanes by sp3-sp2 Suzuki-Miyaura and Chan-Evans-Lam Coupling Reactions of Tertiary Trifluoroborates.
Harris MR, et al.
Organic Letters, 19(9), 2450-2453 (2017)
A Modular Approach to the Synthesis of gem-Disubstituted Cyclopropanes.
Harris MR, et al.
Organic Letters, 20(10), 2867-2871 (2018)
The use of carboxylic acids as traceless directing groups for regioselective C-H bond functionalisation.
Font M and Quibell
Chemical Communications (Cambridge, England), 53(41), 5584-5597 (2017)
Pd-Catalyzed Carbonylative Carboperfluoroalkylation of Alkynes. Through-Space 13C-19F Coupling as a Probe for Configuration Assignment of Fluoroalkyl-Substituted Olefins.
Domanski S, et al.
The Journal of Organic Chemistry, 82(15), 7998-8007 (2017)
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