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Merck
CN
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文件

760110

Sigma-Aldrich

4-氰基-4-[(十二烷基磺胺基硫代羰基)磺胺基]戊醇

别名:

Dodecyl Thiol Cyano Thiol

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About This Item

经验公式（希尔记法）:
C19H35NOS3
分子量:
389.68
MDL编号:
MFCD22417215
UNSPSC代码:
12162002
PubChem化学物质编号:
329766838
NACRES:
NA.23

检测方案

≥96.5% (HPLC)

质量水平

100

形式

solid or liquid (Powder or Solid or Crystals or Chunk(s) or Semi-solid or Liquid)

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)(CCCO)C#N

InChI

1S/C19H35NOS3/c1-3-4-5-6-7-8-9-10-11-12-16-23-18(22)24-19(2,17-20)14-13-15-21/h21H,3-16H2,1-2H3

InChI key

SAFBIHFUHZPVOZ-UHFFFAOYSA-N

相关类别

一般描述

可逆加成-断裂链转移（RAFT）聚合是一种制备窄分布复杂结构聚合物的方法。4-氰基-4-[（十二烷基磺酰基硫代羰基）磺酰基] 戊醇是一种羟基官能化三硫代碳酸盐筏试剂。用作 RAFT 和开环聚合的双引发剂，以形成明确定义的嵌段共聚物。它们能很好地控制各种乙烯基单体的聚合。

应用

嵌段共聚物 RAFT 和开环聚合的引发剂—这些嵌段共聚物来自于乙烯、金属离子、丙烯酰胺和环状单体的乙烯单体。

特点和优势

水解稳定性好，适用于各种单体及反应条件。

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H301

危险分类

Acute Tox. 3 Oral

WGK

WGK 3

闪点(°F)

No data available

闪点(°C)

No data available

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Thiocarbonylthio compounds (SC (Z) SR) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization).
Chiefari, J., Mayadunne, R. T., Moad, C. L., Moad, G., Rizzardo, E., Postma, A., & Thang, S. H.
Macromolecules, 36(7), 2273-2283 (2003)
One-step synthesis of block copolymers using a hydroxyl-functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H.
Journal of Polymer Science Part A: Polymer Chemistry, 51(4), 774-779 (2013)
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

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