推荐产品
![2-{双[3,5-双(三氟甲基)苯基]膦基}-3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯 95%](/deepweb/assets/sigmaaldrich/product/structures/371/999/7169f55f-ccbe-4696-bbdb-ab785b331b2e/640/7169f55f-ccbe-4696-bbdb-ab785b331b2e.png)
质量水平
检测方案
98%
形式
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
mp
108-113 °C
官能团
phosphine
SMILES字符串
CN(C)C(C=CC=C1N(C)C)=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4
InChI
1S/C28H41N2P/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23/h11-13,18-23H,5-10,14-17H2,1-4H3
InChI key
DRNAQRXLOSUHBQ-UHFFFAOYSA-N
应用
在 3-环戊基吲哚衍生物 二氢苯并呋喃 和 反式 双环磺酰胺的钯催化合成中，CPhos 可作为配体使用
- 。
- 合成环钯配合物预催化剂，用于仲烷基锌的 Negishi 偶联。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Synthesis of 2, 3-dihydrobenzofurans via the palladium catalyzed carboalkoxylation of 2-allylphenols.
Hutt JT and Wolfe JP
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 3(10), 1314-1318 (2016)
Palladium-Catalyzed Negishi Coupling of ?-CF3 Oxiranyl Zincate: Access to Chiral CF3-Substituted Benzylic Tertiary Alcohols.
Zhang H and Buchwald SL
Journal of the American Chemical Society, 139(33), 11590-11594 (2017)
Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides.
Han C and Buchwald SL
Journal of the American Chemical Society, 131(22), 7532-7533 (2009)
Pd-Catalyzed Alkene Carboheteroarylation Reactions for the Synthesis of 3-Cyclopentylindole Derivatives.
Kirsch JK, et al.
The Journal of Organic Chemistry, 83(21), 13568-13573 (2018)
Highly selective palladium-catalyzed cross-coupling of secondary alkylzinc reagents with heteroaryl halides.
Yang Y, et al.
Organic Letters, 16(17), 4638-4641 (2014)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门