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About This Item
经验公式（希尔记法）:
C14H8N4
CAS号:
分子量:
232.24
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
质量水平
检测方案
99% (HPLC)
形式
solid
mp
310-315 °C
SMILES字符串
c1cnc2c(c1)c3nccnc3c4cccnc24
InChI
1S/C14H8N4/c1-3-9-11(15-5-1)12-10(4-2-6-16-12)14-13(9)17-7-8-18-14/h1-8H
InChI key
IBOSPAWVGHGUAV-UHFFFAOYSA-N
一般描述
Pyrazino[2,3-f][1,10]phenanthroline is a ligand which is used in the synthesis of copper(I)- phenanthroline complexes which are used in molecular device technology and in solar-energy conversion. It functions as an electron acceptor and the electron density is delocalized on the quinoxaline ring. The absorption and emission properties and the excited state lifetimes of these phenanthroline based copper complexes can be fine-tuned easily.
应用
- As an electron accepting ligand in metal complexes which are used in solar cells.
- Used in the synthesis of ruthenium (II) complexes which are used as DNA probes.
特点和优势
Imparts improved directionality of electron transfer in excited copper complexes.
Yujie Sun et al.
Inorganic chemistry, 47(14), 6427-6434 (2008-06-25)
A series of ruthenium(II) complexes possessing ligands with an extended pi system were synthesized and characterized. The complexes are derived from [Ru(bpy)3](2+) (1, bpy = 2,2'-bipyridine) and include [Ru(bpy)2(tpphz)](2+) (2, tpphz = tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine), [Ru(bpy)2(dppx)](2+) (3, dppx = 7,8-dimethyldipyrido[3,2-a:2',3'-c]phenazine), [Ru(bpy)2(dppm2)](2+) (4
Synthesis, spectroscopic and electrochemical characterization of copper (I) complexes with functionalized pyrazino [2, 3-f]-1, 10-phenanthroline.
Barrientos, L., Araneda, C., Loeb, B., & Crivelli, I. G.
Polyhedron, 27(4), 1287-1295 (2008)
Ge; Hu; Wei;et al.
Journal of Luminescence, 131, 238-243 (2011)
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