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Merck
CN

751626

Sigma-Aldrich

聚(乙二醇)甲醚(4-氰基-4-戊酸十二烷基三硫代碳酸)

average Mn 5,400

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别名:
PEG-RAFT, 十二烷基-三硫代碳酸-氰基PEG, 聚(乙二醇)甲醚4-氰基-4-[(三硫代碳酸酯)磺酰基]戊酸盐
UNSPSC代码:
12352100
NACRES:
NA.23

形式

solid

质量水平

分子量

average Mn 5,400

转变温度

Tm 55-60 °C

PDI

≤1.1

Ω端

4-cyano-4-pentanoate dodecyl trithiocarbonate

α端

methoxy

储存温度

2-8°C

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一般描述

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

应用

RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene, acrylate, and acrylamide monomers to make lithographically and biologically important PEG-block copolymers. Chain Transfer Agent (CTA)

WGK

WGK 3


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)

商品

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

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实验方案

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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