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Merck
CN

749133

Sigma-Aldrich

2-(十二烷基硫代羰基硫代硫基硫基)丙酸

97%

别名:

2- {[(十二烷基硫羰基)碳硫酰胺]硫酸钛}丙酸, 2-(十二烷基硫代羰基硫代硫基硫基)丙酸, DoPAT

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About This Item

经验公式(希尔记法):
C16H30O2S3
分子量:
350.60
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

97%

形式

powder or crystals

mp

78-82 °C

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)C(O)=O

InChI

1S/C16H30O2S3/c1-3-4-5-6-7-8-9-10-11-12-13-20-16(19)21-14(2)15(17)18/h14H,3-13H2,1-2H3,(H,17,18)

InChI key

CFCFZJHCTNKHGJ-UHFFFAOYSA-N

一般描述

需要帮助选择正确的 RAFT 试剂?请查阅单体的 RAFT 试剂兼容性图表

应用

RAFT可控自由基聚合助剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。链转移剂(CTA)

象形图

Exclamation mark

警示用语:

Warning

危险分类

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Connor R Bilchak et al.
ACS nano (2020-11-21)
Polymer membranes are critical to many sustainability applications that require the size-based separation of gas mixtures. Despite their ubiquity, there is a continuing need to selectively affect the transport of different mixture components while enhancing mechanical strength and hindering aging.
Gordana Siljanovska Petreska et al.
Polymers, 12(6) (2020-06-04)
AB diblock waterborne copolymers made of styrene (St) and 2-ethylhexyl acrylate (2EHA) were synthesized by means of two-step reversible addition fragmentation chain transfer (RAFT) (mini)emulsion polymerization. Monofunctional asymmetric RAFT agent was used to initiate the polymerization. The hard polystyrene "A"
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Low-cost, high-purity RAFT Agents are vital for industrial RAFT polymerization. We supply effective agents for this technology.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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