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Merck
CN

746177

Sigma-Aldrich

MIBA

greener alternative

96%

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别名:
5-Methoxy-2-iodophenylboronic acid
经验公式(希尔记法):
C7H8BIO3
CAS号:
分子量:
277.85
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.06

质量水平

检测方案

96%

形式

solid

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

202-207 °C

环保替代产品分类

储存温度

2-8°C

SMILES字符串

OB(O)C1=C(I)C=CC(OC)=C1

InChI

1S/C7H8BIO3/c1-12-5-2-3-7(9)6(4-5)8(10)11/h2-4,10-11H,1H3

InChI key

XQYAEIDOJUNIGY-UHFFFAOYSA-N

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

应用

MIBA can be used to promote direct amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

法律信息

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

相关产品

产品编号
说明
价格

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Raed M Al-Zoubi et al.
Organic letters, 12(11), 2480-2483 (2010-05-11)
A convenient and regioselective silver(I)-mediated electrophilic iodination and bromination reaction of arylboronic acids has been developed. The boronic acid does not require protection prior to the reaction, which can be performed on a multigram scale with moderate to excellent yields.
Zahra Sheikholislam et al.
Iranian journal of pharmaceutical research : IJPR, 12(4), 729-733 (2014-02-14)
Radioiodinated meta-iodobenzylguanidine (MIBG) is one of the important radiopharmaceuticals in Nuclear Medicine. [(123/131)I] MIBG is used for imaging of Adrenal medulla, studying heart sympathetic nerves, treatment of pheochromacytoma and neuroblastoma. For clinical application, radioiodinated MIBG is prepared through isotopic exchange
Nicolas Gernigon et al.
The Journal of organic chemistry, 77(19), 8386-8400 (2012-09-28)
The importance of amides as a component of biomolecules and synthetic products motivates the development of catalytic, direct amidation methods employing free carboxylic acids and amines that circumvent the need for stoichiometric activation or coupling reagents. ortho-Iodophenylboronic acid 4a has
Paulo F Severino et al.
Oncotarget, 8(33), 54506-54517 (2017-09-15)
The sialyl-Tn (sTn) antigen is an
Laura Fattorini et al.
BMC plant biology, 18(1), 182-182 (2018-09-08)
Adventitious roots (ARs) are often necessary for plant survival, and essential for successful micropropagation. In Arabidopsis thaliana dark-grown seedlings AR-formation occurs from the hypocotyl and is enhanced by application of indole-3-butyric acid (IBA) combined with kinetin (Kin). The same IBA + Kin-treatment

相关内容

Research in the Hall Group is centered on organoboron chemistry and explores various applications of boronic acid derivatives in reaction development, catalysis, natural product synthesis, and chemical biology. Hall and his co-workers have pioneered the concept of "Boronic Acid Catalysis” (BAC), an emerging strategy for the direct activation of carboxylic acids and alcohols.

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