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Merck
CN

745146

9-甲基-9 H-芴-9-羰基-13氯化氯

≥97.0% (GC)

别名:

13COgen

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关于此项目

经验公式（希尔记法）:
13CC14H11ClO
化学文摘社编号:
1072315-89-9
分子量:
243.69
NACRES:
NA.22
PubChem Substance ID:
329764967
UNSPSC Code:
12352005
MDL number:
MFCD18839249

主要文件

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产品名称

9-甲基-9 H-芴-9-羰基-13氯化氯, ≥97.0% (GC)

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3/i14+1

SMILES string

CC1(c2ccccc2-c3ccccc13)[13C](Cl)=O

InChI key

ZQYOOHGEBHBNTP-UJKGMGNHSA-N

isotopic purity

≥97.0%

assay

≥97.0% (GC)

form

solid

reaction suitability

reaction type: C-C Bond Formation

functional group

acyl chloride

Quality Level

100

相关类别

Application

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

Other Notes

Frequently Asked Questions are available for this Product.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

新产品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN7639
BCCH5498
BCCG9089
BCCG1189
BCCG4169

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[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Thomas M Gøgsig et al.
Organic letters, 14(10), 2536-2539 (2012-05-09)
The direct carbonylative palladium catalyzed synthesis of monoprotected 1,3-ketoaldehydes is reported starting from aryl iodides applying near stoichiometric amounts of carbon monoxide. Besides representing platforms for a variety of heterocyclic structures, these motives serve as viable precursors for the highly
Korsager, S.;
Angewandte Chemie (International Edition in English) (2013)
Mia N Burhardt et al.
The Journal of organic chemistry, 77(12), 5357-5363 (2012-05-23)
We have synthesized two isotopically labeled variants of the β-amyloid binding compound FSB possessing (13)C-labels on the two terminal aryl carboxylic acid moieties. One of these was also fully deuterated on the olefinic spacers. The (13)C-isotope labeling was achieved applying
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
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