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Merck
CN

745022

9-甲基-9H-芴-9-羰基氯

≥99.0% (GC)

别名:

COgen, 9-Methylfluorene-9-carbonyl chloride

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关于此项目

经验公式(希尔记法):
C15H11ClO
化学文摘社编号:
分子量:
242.70
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5266487
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产品名称

9-甲基-9H-芴-9-羰基氯, ≥99.0% (GC)

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3

SMILES string

CC1(C(Cl)=O)c2ccccc2-c3ccccc13

InChI key

ZQYOOHGEBHBNTP-UHFFFAOYSA-N

assay

≥99.0% (GC)

form

solid

reaction suitability

reaction type: C-C Bond Formation

functional group

acyl chloride

Quality Level

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Application

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

Other Notes

Frequently Asked Questions are available for this Product.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
Korsager, S.;
Angewandte Chemie (International Edition in English) (2013)
Thomas M Gøgsig et al.
Organic letters, 14(10), 2536-2539 (2012-05-09)
The direct carbonylative palladium catalyzed synthesis of monoprotected 1,3-ketoaldehydes is reported starting from aryl iodides applying near stoichiometric amounts of carbon monoxide. Besides representing platforms for a variety of heterocyclic structures, these motives serve as viable precursors for the highly
Mia N Burhardt et al.
The Journal of organic chemistry, 77(12), 5357-5363 (2012-05-23)
We have synthesized two isotopically labeled variants of the β-amyloid binding compound FSB possessing (13)C-labels on the two terminal aryl carboxylic acid moieties. One of these was also fully deuterated on the olefinic spacers. The (13)C-isotope labeling was achieved applying

商品

Studies in the field of carbonylation chemistry led to the discovery of a novel carbon monoxide (CO) delivery system.

What is COgen? What is COware? What is the SyTracks COgenerator system? And more questions answered.

相关内容

The Skrydstrup group has developed reagents and glassware for carrying out transition metal catalyzed carbonylations in a simple and safe manner.

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