所有图片(1)
About This Item
经验公式（希尔记法）:
C7H7N3
CAS号:
分子量:
133.15
Beilstein:
636825
MDL编号:
UNSPSC代码:
12352125
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
≥95.0% (HPLC)
表单
solution
浓度
~0.5 M in dichloromethane
杂质
≤2.0% water
储存温度
2-8°C
SMILES字符串
[N-]=[N+]=NCc1ccccc1
InChI
1S/C7H7N3/c8-10-9-6-7-4-2-1-3-5-7/h1-5H,6H2
InChI key
UDLLFLQFQMACJB-UHFFFAOYSA-N
一般描述
苄基叠氮化物是一种芳族叠氮化物，常用于铜(I)催化的叠氮化物-炔烃环加成反应。
应用
- Synthesis of Estrone Heterodimers and Evaluation of Their In Vitro Antiproliferative Activity.：研究用苄基叠氮为关键试剂合成具有显著抗增殖活性的雌激素异二聚体，说明它在医药中间体合成中的应用潜力(Bózsity N et al., 2024)。
- Fluoride Abstraction Induced by Tris(pentafluoroethyl)difluorophosphorane: A Convenient Way to Synthesize Cationic N-Heterocyclic Carbene- and Cyclic (Alkyl)(amino)carbene-Ligated Copper Alkyne and Arene Complexes.：该文描述了用苄基叠氮合成炔或脂芳烃的铜复合物的方法，强调它在创新点击化学应用中的作用(Riethmann M et al., 2024)。
警示用语：
Warning
危险分类
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
靶器官
Central nervous system
储存分类代码
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Lachlan S Campbell-Verduyn et al.
Chemical communications (Cambridge, England), 16(16), 2139-2141 (2009-04-11)
Monodentate phosphoramidite ligands are used to accelerate the copper(i)-catalyzed 1,3-dipolar cycloaddition of azides and alkynes (CuAAC) rapidly yielding a wide variety of functionalized 1,4-disubstituted-1,2,3-triazoles; Cu(i) and Cu(ii) salts both function as the copper source in aqueous solution to provide excellent
Cu-catalyzed azide? alkyne cycloaddition
Meldal M & Torn?e CW
Chemical Reviews, 108(8), 2952-3015 (2008)
Tommy Siu-Ming Tang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(30), 10729-10740 (2015-06-23)
The synthesis, characterization, photophysics, lipophilicity, and cellular properties of new phosphorescent ruthenium(II) polypyridine complexes functionalized with a dibenzocyclooctyne (DIBO) or amine moiety [Ru(N^N)2 (L)](PF6 )2 are reported (L=4-(13-N-(3,4:7,8-dibenzocyclooctyne-5-oxycarbonyl) amino-4,7,10-trioxa-tridecanyl-aminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-DIBO, N^N=2,2'-bipyridine bpy (1 a), 1,10-phenanthroline phen (2 a); L=4-(13-amino-4,7,10-trioxa-tridecanylaminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-NH2 , N^N=bpy
Daniel Zewge et al.
Bioconjugate chemistry, 25(12), 2222-2232 (2014-11-15)
Chemical modification of siRNA is achieved in a high-throughput manner (96-well plate format) by copper catalyzed azide-alkyne cycloadditions. This transformation can be performed in one synthetic operation at up to four positions with complete specificity, good yield, and acceptable purity.
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