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安全信息

742430

Sigma-Aldrich

疊氮苄 溶液

~0.5 M in dichloromethane, ≥95.0% (HPLC)

别名:

苄基叠氮 溶液, 苯甲基叠氮 溶液

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1 G
CN¥479.76
50 G
CN¥1,195.10

CN¥479.76

国内现货，预计发货时间April 27, 2025详情

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1 G
CN¥479.76
50 G
CN¥1,195.10

About This Item

经验公式（希尔记法）:
C7H7N3
CAS号:
622-79-7
分子量:
133.15
Beilstein:
636825
MDL编号:
MFCD00013836
UNSPSC代码:
12352125
PubChem化学物质编号:
329765573
NACRES:
NA.22

CN¥479.76

国内现货，预计发货时间April 27, 2025详情

获取大包装报价

质量水平

100

方案

≥95.0% (HPLC)

表单

solution

浓度

~0.5 M in dichloromethane

杂质

≤2.0% water

储存温度

2-8°C

SMILES字符串

[N-]=[N+]=NCc1ccccc1

InChI

1S/C7H7N3/c8-10-9-6-7-4-2-1-3-5-7/h1-5H,6H2

InChI key

UDLLFLQFQMACJB-UHFFFAOYSA-N

相关类别

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此商品
PHR134110918541131
Saccharin ≥99%

240931

Saccharin

Saccharin Pharmaceutical Secondary Standard; Certified Reference Material

PHR1341

Saccharin

Saccharin ≥98%

109185

Saccharin

Mettler-Toledo Calibration substance ME 51143091, Saccharin traceable to primary standards (LGC)

41131

Mettler-Toledo Calibration substance ME 51143091, Saccharin

assay

≥99%

assay

-

assay

≥98%

assay

-

Quality Level

200

Quality Level

300

Quality Level

100

Quality Level

100

solubility

acetone: 1g in 12mL(lit.), boiling water: 1g in 25mL(lit.), alcohol: 1g in 31mL(lit.)

solubility

-

solubility

H2O: soluble 1g in 290ml, acetone: soluble 1g in 12ml, alcohol: soluble 1g in 31ml, boiling water: soluble 1g in 25ml, glycerol: soluble 1g in 50ml, alcohol: very slightly soluble, chloroform: slightly soluble, diethyl ether: slightly soluble

solubility

-

mp

226-229 °C (lit.)

mp

226-229 °C (lit.)

mp

226-229 °C (lit.)

mp

226-229 °C (lit.)

form

powder

form

-

form

-

form

-

一般描述

苄基叠氮化物是一种芳族叠氮化物，常用于铜(I)催化的叠氮化物-炔烃环加成反应。[1]

应用

  • Synthesis of Estrone Heterodimers and Evaluation of Their In Vitro Antiproliferative Activity.：研究用苄基叠氮为关键试剂合成具有显著抗增殖活性的雌激素异二聚体，说明它在医药中间体合成中的应用潜力(Bózsity N et al., 2024)。
  • Fluoride Abstraction Induced by Tris(pentafluoroethyl)difluorophosphorane: A Convenient Way to Synthesize Cationic N-Heterocyclic Carbene- and Cyclic (Alkyl)(amino)carbene-Ligated Copper Alkyne and Arene Complexes.：该文描述了用苄基叠氮合成炔或脂芳烃的铜复合物的方法，强调它在创新点击化学应用中的作用(Riethmann M et al., 2024)。

象形图

Health hazardExclamation mark
GHS08,GHS07

警示用语：

Warning

危险分类

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品
  • 技术规格说明书

    • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number
    BCCB3315
    BCBL4667V
    BCBL2329V
    BCBJ9254V
    BCBF8788V

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    Lachlan S Campbell-Verduyn et al.
    Chemical communications (Cambridge, England), 16(16), 2139-2141 (2009-04-11)
    Monodentate phosphoramidite ligands are used to accelerate the copper(i)-catalyzed 1,3-dipolar cycloaddition of azides and alkynes (CuAAC) rapidly yielding a wide variety of functionalized 1,4-disubstituted-1,2,3-triazoles; Cu(i) and Cu(ii) salts both function as the copper source in aqueous solution to provide excellent
    Cu-catalyzed azide? alkyne cycloaddition
    Meldal M & Torn?e CW
    Chemical Reviews, 108(8), 2952-3015 (2008)
    Tommy Siu-Ming Tang et al.
    Chemistry (Weinheim an der Bergstrasse, Germany), 21(30), 10729-10740 (2015-06-23)
    The synthesis, characterization, photophysics, lipophilicity, and cellular properties of new phosphorescent ruthenium(II) polypyridine complexes functionalized with a dibenzocyclooctyne (DIBO) or amine moiety [Ru(N^N)2 (L)](PF6 )2 are reported (L=4-(13-N-(3,4:7,8-dibenzocyclooctyne-5-oxycarbonyl) amino-4,7,10-trioxa-tridecanyl-aminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-DIBO, N^N=2,2'-bipyridine bpy (1 a), 1,10-phenanthroline phen (2 a); L=4-(13-amino-4,7,10-trioxa-tridecanylaminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-NH2 , N^N=bpy
    Daniel Zewge et al.
    Bioconjugate chemistry, 25(12), 2222-2232 (2014-11-15)
    Chemical modification of siRNA is achieved in a high-throughput manner (96-well plate format) by copper catalyzed azide-alkyne cycloadditions. This transformation can be performed in one synthetic operation at up to four positions with complete specificity, good yield, and acceptable purity.

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