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Merck
CN

741035

Sigma-Aldrich

2-十二烷基硫代羰基硫代-2-甲基丙酸N-羟基琥珀酰亚胺酯

98% (HPLC)

别名:

N-羟基琥珀酰亚胺2-(十二烷基硫基硫代羰基硫基)异丁酸酯

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About This Item

经验公式(希尔记法):
C21H35NO4S3
分子量:
461.70
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

98% (HPLC)

形式

solid

mp

96-102 °C

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)ON1C(=O)CCC1=O

InChI

1S/C21H35NO4S3/c1-4-5-6-7-8-9-10-11-12-13-16-28-20(27)29-21(2,3)19(25)26-22-17(23)14-15-18(22)24/h4-16H2,1-3H3

InChI key

HKWLQDYVQCZTQP-UHFFFAOYSA-N

一般描述

需要帮助选择正确的RAFT试剂?请查阅RAFT试剂与单体的相容性表

应用

用于受控自由基聚合的官能化RAFT试剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。NHS酯末端可用于与多种生物分子偶联。链转移剂(CTA)。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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